Core-Shell Graphitic Carbon Nitride/Zinc Phytate as a Novel Efficient Flame Retardant for Fire Safety and Smoke Suppression in Epoxy Resin

Zhang, Weiwei; Wu, Weihong; Meng, Weihua; Xie, Weiya; Cui, Yumeng; Xu, Jianzhong

doi:10.3390/polym12010212

Cited by 24 publications

(10 citation statements)

References 39 publications

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“…The TSP curves demonstrated that, after the flame retardant coating, the TSP value greatly decreased from 10.99 m 2 for neat EPS to 0.457, 0.196, 0.394, and 0.133 m 2 for EPS/IFR1, EPS/IFR2, EPS/IFR3, and EPS/MDI/IFR3, respectively as shown in Figure 5 d and Table 3 . The substantial reduction in TSP demonstrated that the water-based intumescent flame retardant coatings effectively suppressed smoke formation, which would remarkably increase the chances of people escaping in a fire [ 59 ].…”

Section: Resultsmentioning

confidence: 99%

Expanded Polystyrene Beads Coated with Intumescent Flame Retardant Material to Achieve Fire Safety Standards

Bhoite

Kim²,

Jo³

et al. 2021

Polymers

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The compatibility and coating ratio between flame retardant materials and expanded polystyrene (EPS) foam is a major impediment to achieving satisfactory flame retardant performance. In this study, we prepared a water-based intumescent flame retardant system and methylene diphenyl diisocyanate (MDI)-coated expandable polystyrene microspheres by a simple coating approach. We investigated the compatibility, coating ratio, and fire performance of EPS- and MDI-coated EPS foam using a water-based intumescent flame retardant system. The microscopic study revealed that the water-based intumescent flame retardant materials were successfully incorporated with and without MDI-coated EPS microspheres. The cone calorimeter tests (CCTs) of the MDI-coated EPS containing water-based intumescent flame retardant materials exhibited better flame retardant performance with a lower total heat release (THR) 7.3 MJ/m2, peak heat release rate (PHRR) 57.6 kW/m2, fire growth rate (FIGRA) 2027.067 W/m2.s, and total smoke production (TSP) 0.133 m2. Our results demonstrated that the MDI-coated EPS containing water-based intumescent flame retardant materials achieved flame retarding properties as per fire safety standards.

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Section: Resultsmentioning

confidence: 99%

Expanded Polystyrene Beads Coated with Intumescent Flame Retardant Material to Achieve Fire Safety Standards

Bhoite

Kim²,

Jo³

et al. 2021

Polymers

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“…A lot of research works have been carried out, and the direct addition of flame retardants has the advantages of convenience and economy, thus becoming the most chosen approach. Halogen flame retardant has advantages of high flame retardant efficiency [ 16 ], low dosage and good compatibility with materials, however, a large amount of smoke and poisonous and corrosive gases, such as dioxins, will be produced during combustion, causing great harm to the environment. Moreover, metal hydroxide is also an available flame retardant synergist, which is non-toxic and has good stability, while plenty of additive amounts and poor flowability will reduce the mechanical properties of materials.…”

Section: Introductionmentioning

confidence: 99%

Synergistic Flame Retardant Effect of Barium Phytate and Intumescent Flame Retardant for Epoxy Resin

et al. 2021

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Recently, widespread concern has been aroused on environmentally friendly materials. In this article, barium phytate (Pa-Ba) was prepared by the reaction of phytic acid with barium carbonate in deionized water, which was used to blend with intumescent flame retardant (IFR) as a flame retardant and was added to epoxy resin (EP). Afterward, the chemical structure and thermal stability of Pa-Ba were characterized by Fourier transform infrared (FTIR) spectroscopy and thermogravimetric analysis (TGA), respectively. On this basis, the flammability and flame retardancy of EP composites were researched. It is shown that EP/14IFR/2Ba composite has the highest limiting oxygen index (LOI) value of 30.7%. Moreover, the peak heat release rate (PHRR) of EP/14IFR/2Ba decreases by 69.13% compared with pure EP. SEM and Raman spectra reveal the carbonization quality of EP/14IFR/2Ba is better than that of other composites. The results prove that Pa-Ba can cooperate with IFR to improve the flame retardancy of EP, reducing the addition amount of IFR in EP, thus expanding the application range of EP. In conclusion, adding Pa-Ba to IFR is a more environmentally friendly and efficient method compared with others.

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“…In the ablation process, a protective layer is formed in advance to protect the substrate, thereby enhancing the compactness of the substrate. Aluminum hypophosphite (AHP), another type of flame retardant, 35–39 is conducive to form ceramic layer, which may play a role to strengthen char layer 41–46 . Thus, the influence of ZB on the ablative properties of epoxy‐modified silicon rubber and a comparison with AHP‐ and ZB/AHP‐containing counterparts were systematically studied.…”

Section: Introductionmentioning

confidence: 99%

Ablation properties of zinc borate and aluminum hypophosphite filled silicone rubber composites

Zhang

Yan

Wang

et al. 2021

J of Applied Polymer Sci

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The ablative properties of epoxy modified silicone rubber composites filled with zinc borate (ZB) and aluminum hypophosphite (AHP) were studied. The decomposition of the added fillers and covering connection of residual on the substrate contribute to the improvement of heat insulation. The ablation test shows that the formation of a dense char layer with certain strength is key to improving the ablative properties. The optimal ablative performance is achieved when the concentration of ZB and AHP is 10 and 5 phr, respectively. Under such circumstances, the linear ablation rate is as low as 0.032 mm/s, which is about 61% lower than the pure silicone rubber. Furthermore, the structure and composition of the formed char layer were analyzed using X‐ray diffraction analysis, scanning electron microscopy, and Fourier transform infrared spectroscopy.

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Core-Shell Graphitic Carbon Nitride/Zinc Phytate as a Novel Efficient Flame Retardant for Fire Safety and Smoke Suppression in Epoxy Resin

Cited by 24 publications

References 39 publications

Expanded Polystyrene Beads Coated with Intumescent Flame Retardant Material to Achieve Fire Safety Standards

Expanded Polystyrene Beads Coated with Intumescent Flame Retardant Material to Achieve Fire Safety Standards

Synergistic Flame Retardant Effect of Barium Phytate and Intumescent Flame Retardant for Epoxy Resin

Ablation properties of zinc borate and aluminum hypophosphite filled silicone rubber composites

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