Copper(II) Surface-Functionalized Porous Organic Polymers for One-Pot Synthesis of Sulfoxide via Chan-Lam Cross-Coupling and Photooxidation Reactions
Qiuyuan Lin,
Zhiye Zheng,
Shuting Xu
et al.
Abstract:Nanometer-sized porous organic polymers (POPs) composed of 4,4difluoro-4-bora-3a,4a-diaza-s-indacene (BODIPY) and tetraphenylmethane units were synthesized via Sonogashira coupling reactions under mini-emulsion conditions. Furthermore, a post-synthetic strategy was employed to covalently attach copper(II)−phenanthroline complexes to the surface of the POP nanoparticles through a thiol-yne click reaction. Detailed characterization of the photocatalyst, TEPM−BDP−Phen@Cu, using techniques such as solid-state nucl… Show more
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