Copper(II) complexes with derivatives of salen and tetrahydrosalen: a spectroscopic, electrochemical and structural study

Klement, Róbert; Stock, F.; Elias, Horst; Paulus, H.; Pelikán, P.; Valko, Marián; Mazúr, Milan

doi:10.1016/s0277-5387(99)00291-0

Cited by 140 publications

(69 citation statements)

References 73 publications

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“…Copper(II) complexes of N 2 O 2 ligands have generated considerable interest because of their interesting physico-chemical properties, potentially useful in catalytical reaction and biological activities [1,2]. Most of the earlier investigations were carried out with the tetradentate Schiff base ligand salen and its derivatives, while N , N -bis(benzoylacetone)ethylenediimine and their derivatives have rarely been studied.…”

Section: Discussionmentioning

confidence: 99%

Refinement of the crystal structure of N,N'-ethylene-bis(benzoylacetoniminato) copper(II), Cu(C22H22N2O2), at 110 K

Dehghanpour¹,

Mojahed²,

Farzaneh³

2005

Zeitschrift Für Kristallographie - New Crystal Structures

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Section: Discussionmentioning

confidence: 99%

Refinement of the crystal structure of N,N'-ethylene-bis(benzoylacetoniminato) copper(II), Cu(C22H22N2O2), at 110 K

Dehghanpour¹,

Mojahed²,

Farzaneh³

2005

Zeitschrift Für Kristallographie - New Crystal Structures

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show abstract

“…Copper(II) complexes of N2O2 ligands have generated considerable interest because of their interesting physico-chemical properties, potentially useful in catalytical reaction and biological activities [ 1,2]. Most of the earlier investigations were carried out with the tetradentate Schiff base ligand salen and its derivatives, while N y N'-bis(benzoylacetone)ethylenediimine and their derivatives have rarely been studied.…”

Section: Discussionmentioning

confidence: 99%

Refinement of the crystal structure of N,N' -ethylene-bis(benzoylacetoniminato) copper(II), Cu(C22H22N2O2), at 110 Κ

Dehghanpour¹,

Mojahed²,

Farzaneh³

2005

Zeitschrift Für Kristallographie - New Crystal Structures

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“…Recrystallization from ethanol afforded single crystals suitable for X-ray structure determination. C 25 Fig. 1.…”

Section: Preparation Of Nn'-bis(2-hydroxy-1-naphthylmethylidene)-1-mmentioning

confidence: 99%

Synthesis, Structure, Spectroscopic Studies And Ab-Initio Calculations On First Hyperpolarizabilities Of N,N’-Bis(2-Hydroxy-1-Naphthylmethylidene)- 1-Methyl-1,2-Diaminoethane-N,N’,O,O’-Copper(Ii)

Karakas

Elmalı

Ünver

et al. 2006

Zeitschrift Für Naturforschung B

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N,N'-Bis(2-hydroxy-1-naphthylmethylidene)-1-methyl-1,2-diaminoethane-N,N',O,O'-copper(II) has been synthesized, and characterized by FT-IR and UV/vis spectroscopies. Its crystal structure has been determined by X-ray diffraction analysis. The maximum absorption wavelengths recorded by linear optical experiments are estimated in the UV region to be shorter than 450 nm, showing good optical transparency to the visible light. It may thus possess first hyperpolarizabilities with non-zero values for nonlinear optical (NLO) applications. Ab-initio quantum chemical calculations of the electric dipole moments (µ) and the first static hyperpolarizabilities (β ) were carried out. The computational results suggest that the complex may indeed have microscopic NLO behavior with non-zero values.

show abstract

Copper(II) complexes with derivatives of salen and tetrahydrosalen: a spectroscopic, electrochemical and structural study

Cited by 140 publications

References 73 publications

Refinement of the crystal structure of N,N'-ethylene-bis(benzoylacetoniminato) copper(II), Cu(C22H22N2O2), at 110 K

Refinement of the crystal structure of N,N'-ethylene-bis(benzoylacetoniminato) copper(II), Cu(C22H22N2O2), at 110 K

Refinement of the crystal structure of N,N' -ethylene-bis(benzoylacetoniminato) copper(II), Cu(C22H22N2O2), at 110 Κ

Synthesis, Structure, Spectroscopic Studies And Ab-Initio Calculations On First Hyperpolarizabilities Of N,N’-Bis(2-Hydroxy-1-Naphthylmethylidene)- 1-Methyl-1,2-Diaminoethane-N,N’,O,O’-Copper(Ii)

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