Copper(II) Acetate

Safe-and-Sustainable-by-Design Framework Based on a Prospective Life Cycle Assessment: Lessons Learned from a Nano-Titanium Dioxide Case Study

“…Nano-coating using the atomic layer deposition method was performed with a home-built fluidized bed reactor [ 49 , 50 ]. P25-TiO 2 and a high-grade copper(I) hexafluoropentanedionate–vinyltrimethylsilane complex (Cu(I)(hfac)(TMVS)) [ 51 , 52 , 53 ] were used in the nano-coating process with nitrogen and distilled water [ 54 ]. The product was nano-coated Cu 2 O/P25-TiO 2 and the precursor’s part that did not coat P25-TiO 2 was burned and released as CO 2 and water.…”

A synergistic {Cu2-W12O40} catalyst with high conversion for homo-coupling of terminal alkynes

“…25 1 was also comparable to well-established Cu-based catalysis of Glaser or Hay couplings. 15 (see Table S2†) What's more, this work provides new ideas for the structural design, synthesis and application of heterometallic POM-based functional materials, and also sets up a model for the effective electron transfer in catalytic applications.…”

“…For example, Cu 2 (OAc) 4 (H 2 O) 2 can catalyze the coupling of two terminal alkynes, the product of which is 1,3-diacetylene, Cu 2 (OAc) 4 + 2 RCCH → 2 CuOAc + RCC–CCR + 2 HOAc. 15 For this dimeric unit structure, other small molecular ligands like dioxanes, pyridines, and aniline can all replace the water molecules in the above dimer, 16,17 however, the inorganic nano-sized polyoxometalates (POMs) as molecular ligands have not been reported yet.…”