2020
DOI: 10.1016/s1872-2067(20)63605-1
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Copper-ceria solid solution with improved catalytic activity for hydrogenation of CO2 to CH3OH

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Cited by 50 publications
(47 citation statements)
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References 32 publications
(73 reference statements)
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“…In fact, copper can be easily incorporated into the ceria lattice, improving the redox properties of CeO 2 −Al 2 O 3 supported catalysts by means of the presence of redox pairs (i.e., Cu 2+ /Cu + , Cu 2+ /Cu 0 , and Ce 4+ /Ce 3+ ). 12,24 Moreover, the mixed framework of support provides better active metal dispersion when compared to bare alumina supports. 12 Under these premises, this study presents a series of multicomponent Fe−Cu/CeO 2 −Al 2 O 3 catalysts with various Fe/Cu oxide ratios to deliver an optimal RWGS catalytic formulation.…”
Section: ■ Introductionmentioning
confidence: 99%
“…In fact, copper can be easily incorporated into the ceria lattice, improving the redox properties of CeO 2 −Al 2 O 3 supported catalysts by means of the presence of redox pairs (i.e., Cu 2+ /Cu + , Cu 2+ /Cu 0 , and Ce 4+ /Ce 3+ ). 12,24 Moreover, the mixed framework of support provides better active metal dispersion when compared to bare alumina supports. 12 Under these premises, this study presents a series of multicomponent Fe−Cu/CeO 2 −Al 2 O 3 catalysts with various Fe/Cu oxide ratios to deliver an optimal RWGS catalytic formulation.…”
Section: ■ Introductionmentioning
confidence: 99%
“…7(5) were 0.27 nm, 0.31 nm and 0.23 nm, corresponding to the (200) and (111) lattice planes of CeO 2 and (111) lattice planes of CuO. 31 However, there no MnO x phase observed in Fig. 7(5) , this could be explained by the high dispersion of MnO x due to the low loading.…”
Section: Resultsmentioning
confidence: 92%
“…When introduced MnO x or Fe 2 O 3 , the diffraction peaks of CuO disappeared, indicating the CuO species were dispersed well as amorphous oxides or some Cu species doped into the lattice of CeO 2 and formed Cu–Ce–O solid solution. 31 CuO and MnO x species could strengthen the synergy between CuO and CeO 2 support to restrain the growth of CuO particles. Combined with catalytic activity test results, it could be deduced the bimetal synergistic effect could improve samples' activity by strengthening the interaction between metal oxides and supports.…”
Section: Resultsmentioning
confidence: 99%
“…The control CO 2 in the atmosphere is a serious problem. Recently, converting CO 2 into organic fuels, such as formate, [ 1 ] CH 3 OH, [ 2 ] CH 4 , [ 3 ] and HCHO, [ 4 ] is considered as a exploitable solution to improve the pollution of the environment purification and energy demanded.…”
Section: Introductionmentioning
confidence: 99%
“…This study provides a mild hydrolysis-ultrasonic method for environmental remediation and converting energy using cost-effective semiconductor materials. Recently, converting CO 2 into organic fuels, such as formate, [1] CH 3 OH, [2] CH 4 , [3] and HCHO, [4] is considered as a exploitable solution to improve the pollution of the environment purification and energy demanded.Up to now, numerous methods such as photocatalytic reduction, electrocatalytic reduction, biological transformation,…”
mentioning
confidence: 99%