“…A good deal of literature exists for charge-separated halobismuthate(III) and haloantimonate(III) salts, − ,,− much of it with alkali or organic ammonium cations. Additionally, there are multiple reports of halobismuthate and haloantimonate anions containing Cu(I) or Ag(I), such as Bi 2 Cu 2 I 10 2– , or paired with Cu(I) or Ag(I) cations, ,− many of which show relatively small band gaps. However, neutral ligand-supported iodobismuthate/cuprate and iodoantimonate/cuprate compounds remain extraordinarily rare.…”