Oxygen-isotope effect has been investigated in a recently discovered superconductor Sr 0.4 K 0.6 BiO 3 . This compound has a distorted perovskite structure and becomes superconducting at about 12 K. Upon replacing 16 O with 18 O by 60-80%, the T c of the sample is shifted down by 0.32-0.50 K, corresponding to an isotope exponent of α O = 0.40(5). This isotope exponent is very close to that for a similar bismuthate superconductor Ba 1−x K x BiO 3 with T c = 30 K. The very distinctive doping and T c dependencies of α O observed in bismuthates and cuprates suggest that bismuthates should belong to conventional phonon-mediated superconductors while cuprates might be unconventional supercondutors.
1The discovery of high-temperature superconductivity near 30 K in the nonmagnetic cubic perovskite oxide Ba 1−x K x BiO 3 (BKBO) [1,2] raises an interesting question of whether the layered structure and strong antiferromagnetic correlation in cuprates are essential for hightemperature superconductivity. In order to answer this question, it is important to find some common and distinct features in both systems. The band-structure calculations [3] suggest that the bare density of states at Fermi level in BKBO is at least 3 times smaller than that in cuprates. Since tunneling and extensive oxygen-isotope experiments on BKBO [4][5][6][7][8] seem to indicate that this material is a conventional phonon-mediated superconductor with an electron-phonon coupling constant λ ∼ 1, one might argue that 100 K superconductivity in cuprates could be understood even within the conventional theory with λ ∼ 3. If this were the case, the isotope effects in both cuprates and bismuthates would be similar. As a matter of fact, the oxygen-isotope exponent α O in BKBO has a maximum at optimal doping where T c is the highest [8], while α O in optimally-doped cuprates is the smallest [9][10][11][12]. Moreover, the isovalent substitution of Ca for Sr in the single-layer La 2−x Sr x CuO 4 system leads to a large decrease in T c , and to a large increase in α O [13]. Similarly, the isovalent substitution of Sr for Ba in YBa 2 Cu 3 O 7 gives rise to a strong suppression of superconductivity from 93 K to 60 K [14], and α O also increases with decreasing T c [15]. If the pairing mechanism in bismuthates and cuprates were the same, this unusual T c dependence of α O would also exist in bismuthates.The isovalent substitution of Sr for Ba in Ba 1−x K x BiO 3 cannot be realized using conventional solid-state reaction. Until recently, a new family of bismuth-oxide-based superconductor Sr 1−x K x BiO 3 (SKBO) has been synthesized by a high pressure technique [16]. This material has a distorted perovskite structure and exhibits a superconductivity at about 12 K, which is much lower than that in Ba 1−x K x BiO 3 . It appears that the isovalent substitution effects on T c in both YBa 2 Cu 3 O 7 and Ba 1−x K x BiO 3 are quite similar. Now the important question is whether α O in optimally-doped Sr 1−x K x BiO 3 remains the same or increases substantially comp...