Copolymers based on (p-vinylphenyl)cyclopropylmethyl chlorocinnamate and methyl methacrylate

Guliyev, K. G.; Aliyeva, A. M.; Ponomareva, G. Z.; Sadygova, A. I.; Mamedli, S. B.; Guliyev, A. M.

doi:10.1134/s1070427217020161

Cited by 2 publications

(2 citation statements)

References 5 publications

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“…1, the copolymerization constant values characterize the large activity of PCCC in comparison with styrene. This fact has been apparently connected with availability of conjugation of cyclopropane cycle with substituents in the investigated monomer, which is agreed with data of work [10], as far as an introduction of cyclopropane with substituent in para position of styrene causes the great changes in the electronic structure of molecule.…”

Section: Methodssupporting

confidence: 90%

Synthesis, Radical Copolymerization of (p-vinylphenyl)cyclopropyl chlorocinnamate with Styrene and Photosensitivity of the Prepared Copolymer

Guliyev¹,

Aliyeva²,

Nurullayeva³

et al. 2015

CBU J of Sci

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The radical copolymerization of of (p-vinylphenyl)cyclopropyl chlorocinnamate with styrene has been studied. The new cyclopropane-containing photosensitive copolymer has been prepared. The composition and structure of the synthesized copolymer have been established, the constant values of relative activity of monomers have been determined and the parameters Q-e have been calculated. The dependence of photosensitivity on composition of copolymer has been revealed.

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Section: Methodssupporting

confidence: 90%

Synthesis, Radical Copolymerization of (p-vinylphenyl)cyclopropyl chlorocinnamate with Styrene and Photosensitivity of the Prepared Copolymer

Guliyev¹,

Aliyeva²,

Nurullayeva³

et al. 2015

CBU J of Sci

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“…The constant values of relative activity (Table 1) evidence about large reactivity of PCPC in comparison with MMA, which has been connected with influence of substituent of cyclopropane ring on electron density of double bond of vinyl group [17]. The ester group is included in general system of conjugation, causing redistribution of electron density both in monomer and in radical center forming from it.…”

Section: Resultsmentioning

confidence: 91%

Investigation of Photosensitivity of Copolymer with (P-Vinyl Phenyl) Cyclopropyl Methyl Cinnamate

Guliyev¹

2015

AJAC

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The radical copolymerization of (p-vinyl phenyl) cyclopropyl methyl cinnamate with methyl methacrylate has been studied. New cyclopropane-containing photosensitive copolymers have been prepared. The constant values of relative activity of monomers have been determined and the parameters of Q-e on Alfrey and Price have been calculated. The copolymerization constants of this compound (r1) with methyl methacrylate (r2) calculated on Fineman-Ross method are r1 =1.05, r2 = 0.4, respectively; parameter values Q and e: Q1 =2.5, e1 =-0.9, respectively. The composition and structure of these copolymers have been established. The photochemical investigations of the synthesized copolymer have been carried out. It has been established that a structuring proceeds due to opening of cyclopropane ring and carbonyl groups and also double bond in cinnamate fragment.

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Copolymers based on (p-vinylphenyl)cyclopropylmethyl chlorocinnamate and methyl methacrylate

Cited by 2 publications

References 5 publications

Synthesis, Radical Copolymerization of (p-vinylphenyl)cyclopropyl chlorocinnamate with Styrene and Photosensitivity of the Prepared Copolymer

Synthesis, Radical Copolymerization of (p-vinylphenyl)cyclopropyl chlorocinnamate with Styrene and Photosensitivity of the Prepared Copolymer

Investigation of Photosensitivity of Copolymer with (P-Vinyl Phenyl) Cyclopropyl Methyl Cinnamate

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