Copolymerizations of N-vinylpyrrolidone and activated esters of unsaturated acids

Назарова, О. В.; Solovskij, M. V.; Panarin, E. F.; Денисов, В. М.; Хачатуров, А. С.; Kol'tsov, A. I.; Purkina, A.V.

doi:10.1016/0014-3057(92)90243-u

Cited by 17 publications

(7 citation statements)

References 3 publications

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“…2‐Hydroxy‐2‐methylpropiophenone (Darocur‐1173; 97% pure), used as an initiator, was obtained from Merck‐Schuchard (Hohenbrunn, Germany). HPIEAA was synthesized from acryloyl chloride and N ‐hydroxyphthalimide in the presence of triethylamine in tetrahydrofuran according to a method published elsewhere 27. Purified mouse immunoglobulin G (IgG) was obtained from Zytomed (Berlin, Germany); goat anti‐mouse IgG conjugated with Alexa Fluor 555 was purchased from Molecular Probes (Eugene, OR).…”

Section: Methodsmentioning

confidence: 99%

“…HPIEAA was synthesized from acryloyl chloride and N-hydroxyphthalimide in the presence of triethylamine in tetrahydrofuran according to a method published elsewhere. 27 Purified mouse immunoglobulin G (IgG) was obtained from Zytomed (Berlin, Germany); goat anti-mouse IgG conjugated with Alexa Fluor 555 was purchased from Molecular Probes (Eugene, OR). TopBlock was purchased from Fluka AG (Buchs, Switzerland).…”

Section: Materials and Instrumentsmentioning

confidence: 99%

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Synthesis and investigation of a new macroporous monolithic material based on an N‐hydroxyphthalimide ester of acrylic acid‐co‐glycidyl methacrylate‐co‐ethylene dimethacrylate terpolymer

Slabospitskaya

Влах

Сапрыкина

et al. 2008

J of Applied Polymer Sci

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A macroporous monolithic material based on an N-hydroxyphthalimide ester of acrylic acid-co-glycidyl methacrylate-co-ethylene dimethacrylate terpolymer was synthesized by photoinitiated free-radical polymerization. Several porogenic solvents, such as cyclohexanol, dodecanol, and poly(ethylene glycol)s, were tested to obtain the monolithic material with an optimal pore size allowing unrestricted penetration of large molecule (proteins) into a three-dimensional porous space. The new monolithic material was covalently bound to an inert surface (glass) directly in the polymerization step, and it was suggested as a solid matrix for the development of new types of three-dimensional protein microarrays (biochips). A demonstration of the potential of the suggested microarray platform as well as optimization of microarray performance conditions was realized with a model mouse immunoglobulin G/goat anti-mouse immunoglobulin G affinity pair.

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Section: Methodsmentioning

confidence: 99%

Section: Materials and Instrumentsmentioning

confidence: 99%

Synthesis and investigation of a new macroporous monolithic material based on an N‐hydroxyphthalimide ester of acrylic acid‐co‐glycidyl methacrylate‐co‐ethylene dimethacrylate terpolymer

Slabospitskaya

Влах

Сапрыкина

et al. 2008

J of Applied Polymer Sci

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“…Glycidyl acrylate (GA, >95%) was received from TCI (Hong‐Kong, China). N ‐hydroxyphtalimide ester of acrylic acid (HPIEAA) was synthesized according to protocol published elsewhere 60 . 2‐cyanoethylmethacrylate (CEMA, ≥95%) was kindly donated by Yarsynthez (Yaroslavl, Russia).…”

Section: Experimental Partmentioning

confidence: 99%

Some factors affecting pore size in the synthesis of rigid polymer monoliths: Theory and its applicability

Korzhikova-Vlakh

Tennikova

2021

J of Applied Polymer Sci

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Macroporous monoliths represent now widely used materials whose successful application strongly depends on their characteristics. Among those the average pore size is one of the key parameters. In this paper, we consider the applicability of theoretical calculations for the selection of appropriate porogens to generate the materials with required average pore size. A set of macroporous poly(meth)acrylate monoliths was synthesized via thermo‐ and photo‐initiated free radical polymerization and characterized in regards to their average pore size. Additionally, the difference in solubility parameters as well as Hansen's solubility parameter distance between monomers and porogens were calculated for each polymerization mixture using Hildebrand's and Hansen's solubility theories. The theoretical predications and experimental data were compared and analyzed to establish the applicability of theoretical calculations to previse average pore size for different systems. It was found that Hildebrand's theory seems to be poorly appropriate as universal tool, while Hansen's theoretical approach explained better the efficiency of solvents as porogens. The application of oligomers and polymer solutions due to the increase of viscosity as well as the variation of crosslinker amount in the monomer system can be singled out as Hansen's theory limitations at the prediction of the average pore size.

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“…The use of different molar ratios of the reagents makes it possible to vary the content of CD residues in the polymeric derivative (Table 3, experiments 12, 13). In addition, polymeric ACD derivatives were obtained from VP-CA-NPECA and VP-4 PA-NPE-4 PA copolymers (Table 3, experiments 19,20). Figure 3 depicts the evolution in time for the UV spectra of the reaction mixture (VP-AA-NPEAA copolymer) + CD at 25 and 90°С.…”

Section: Nh 4 Ohmentioning

confidence: 99%

“…The quantity of activated ester units was estimated spectrophotometrically. In the case of p nitrophenyl esters (NPEs) of acrylic acid, crotonic acid, and 4 pentenoic acid (NPEAA, NPECA, and NPE 4 PA, respectively), the absorp tion band corresponding to the bound p nitrophenol (λ max = 274 nm, ε = 9500 l/(mol cm)) was used [21]; in the case of NPIAA, the band at λ max = 295 nm (ε = 2100 l/(mol cm)) was employed [19].…”

Section: Introductionmentioning

confidence: 99%

Water-soluble polymeric derivatives of β-cyclodextrin

et al. 2012

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Copolymerizations of N-vinylpyrrolidone and activated esters of unsaturated acids

Cited by 17 publications

References 3 publications

Synthesis and investigation of a new macroporous monolithic material based on an N‐hydroxyphthalimide ester of acrylic acid‐co‐glycidyl methacrylate‐co‐ethylene dimethacrylate terpolymer

Synthesis and investigation of a new macroporous monolithic material based on an N‐hydroxyphthalimide ester of acrylic acid‐co‐glycidyl methacrylate‐co‐ethylene dimethacrylate terpolymer

Some factors affecting pore size in the synthesis of rigid polymer monoliths: Theory and its applicability

Water-soluble polymeric derivatives of β-cyclodextrin

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