Copolymerization of methyl methacrylate with ethylene in the presence of a VCl4-(iso-C4H9)2AlCl catalyst

Pomogaĭlo, A. D.; Baishiganov, Ye.; D'yachkovskii, F.S.

doi:10.1016/0032-3950(81)90320-8

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“…It was established experimentally that the polymerisation mechanism changes from anionic-coordination to radical during the preparation of diblock copolymers of PE and PMMA. 240 The addition of MMA to the VCl 4 ± AlR 2 Cl catalytic system in the course of anionic-coordination polymerisation of ethylene leads to its inhibition and initiation of the polymerisation of MMA (probably, as a result of radical induced cleavage of the V7C bond). The process results in the PE ± b-PMMA system.…”

Section: In Situ Preparation Of Diblock Chemical Hybridsmentioning

confidence: 99%

Molecular polymer–polymer compositions. Synthetic aspects

Pomogailo¹

2002

Russ. Chem. Rev.

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The main ways of improving the compatibility of The main ways of improving the compatibility of polymer ± polymer compositions containing polyolefins as one polymer ± polymer compositions containing polyolefins as one component are considered. Considerable attention is given to the component are considered. Considerable attention is given to the preparation of polyolefins in the presence of an ingredient bound preparation of polyolefins in the presence of an ingredient bound to the catalyst in the catalytic (including consecutive) polymer-to the catalyst in the catalytic (including consecutive) polymerisation of olefins. The so-called reactor blends and the synthesis isation of olefins. The so-called reactor blends and the synthesis and structure of diblock and conducting composites are described. and structure of diblock and conducting composites are described. The important role of compatibilisation of polymers of different The important role of compatibilisation of polymers of different nature with the use of a third component is pointed out. The nature with the use of a third component is pointed out. The formation mechanism of molecular compositions, the structure formation mechanism of molecular compositions, the structure and properties of the intermediate layer and the main fields of and properties of the intermediate layer and the main fields of application of synthetic polyolefin ± polymer compositions are application of synthetic polyolefin ± polymer compositions are discussed. The bibliography includes 335 references discussed. The bibliography includes 335 references. .

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Section: In Situ Preparation Of Diblock Chemical Hybridsmentioning

confidence: 99%

Molecular polymer–polymer compositions. Synthetic aspects

Pomogailo¹

2002

Russ. Chem. Rev.

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Copolymerization of methyl methacrylate with ethylene in the presence of a VCl4-(iso-C4H9)2AlCl catalyst

Cited by 1 publication

References 11 publications

Molecular polymer–polymer compositions. Synthetic aspects

Molecular polymer–polymer compositions. Synthetic aspects

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