Copolymerization of ethylene with polar styrene monomers catalyzed by phosphino‐dihydronaphtholate neutral nickel catalysts
Fei Wang,
Xu‐ling Wang,
Li Pan
et al.
Abstract:The physical properties of traditional polyolefin materials can be significantly improved by introducing polar groups, especially polar aromatic groups. However, it remains a major challenge to realize the highly effective copolymerization of ethylene with styrene derivatives. In this study, the direct copolymerization of ethylene with various polar styrene monomers bearing functional groups (o‐OMe, m‐OMe, p‐OMe, o‐Cl, m‐Cl, p‐ClSt, o‐F, o‐Br, p‐Me, p‐Ph, p‐Vinyl, p‐COOH, and C6F5) was achieved using phosphino… Show more
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