Coordination polymers with adjustable dimensionality based on CuII and bis-imidazolyl bridging ligand

Synthesis, Crystal Structure, and Luminescent Properties of Novel Zinc Metal–Organic Frameworks Based on 1,3-Bis(1,2,4-triazol-1-yl)propane

“…Bis­(azol-1-yl)­alkanes are neutral nitrogen ligands that are often used to prepare coordination polymers. − Bis­(1,2,4-triazol-1-yl)­alkanes are probably the most widely used among other similar azole derivatives. The system of zinc–carboxylic acid–bis­(1,2,4-triazol-1-yl)­alkane coligand has been explored by several authors; however, in most cases only one-dimensional (1D), 2D, or interpenetrated 3D structures have been prepared, − which prevented the studies of their sorption properties.…”

1,3-Bis(1,2,4-triazol-1-yl)adamantane

“…In previous studies, we used superbasic dimethyl sulfoxide-potassium hydroxide system (DMSO-KOH) for the double alkylation of azoles with high yields [24][25][26][27]. However, our attempt to react 1,3-dibromoadamantane with 1,2,4-triazole in DMSO-KOH was unsuccessful, and only the starting materials were recovered.…”

Fabrication of a polyoxotungstate/metal–organic framework/phosphorus-doped reduced graphene oxide nanohybrid modified glassy carbon electrode by electrochemical reduction and its electrochemical properties

“… 78 The 1,4-bis(imidazole)butane (abbreviated as bimb) was prepared according to the previous literature. 79 Tungstophosphoric acid (H 3 PW 12 O 40 , abbreviated as PW 12 ), cobalt( ii ) nitrate hexahydrate (Co(NO 3 ) 2 ·6H 2 O), terephthalic acid (abbreviated as TPA), dimethylformamide (abbreviated as DMF), graphite powder (<20 μm), and other chemicals were of analytical grade and purchased from commercial sources (Merck or Sigma) and used without further purification. Phosphate buffer saline solutions (PBS, 0.11 M) were prepared by mixing the stock solutions of 0.10 M KCl and 0.01 M H 3 PO 4 and then adjusting the pH with 0.5 M NaOH aqueous solution.…”