Coordination polymer networks with s-block metal ions

Fromm, Katharina M.

doi:10.1016/j.ccr.2007.10.032

Cited by 336 publications

(171 citation statements)

References 98 publications

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Abstract: A number of linear coordination polymers have been assembled from lanthanide cations (Ln 3+ ) and cucurbit [7]

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confidence: 99%

“…X-ray diffraction analysis has revealed that they form three groups of isomorphous structures. Generally, the complexes of Q [7] with light lanthanide cations (those with atomic number below that of neodymium (Nd 3+ )) are in one group. The other two groups, in which the lanthanide cation has atomic number greater than that of europium (Eu 3+ ), seem to follow no obvious rule.…”

mentioning

confidence: 99%

“…The other two groups, in which the lanthanide cation has atomic number greater than that of europium (Eu 3+ ), seem to follow no obvious rule. For example, the complexes of Q [7] with Eu …”

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confidence: 99%

“…Abstract: A number of linear coordination polymers have been assembled from lanthanide cations (Ln 3+ ) and cucurbit [7]uril (Q [7]) in the presence of [ anions acting as inorganic structure inducers in HCl solution. X-ray diffraction analysis has revealed that they form three groups of isomorphous structures.…”

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confidence: 99%

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One-Dimensional Coordination Polymers of Lanthanide Cations to Cucurbit[7]uril Built Using a Range of Tetrachloride Transition-Metal Dianion Structure Inducers

et al. 2013

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“…

Abstract: A number of linear coordination polymers have been assembled from lanthanide cations (Ln 3+ ) and cucurbit [7]

…”

mentioning

confidence: 99%

mentioning

confidence: 99%

“…The other two groups, in which the lanthanide cation has atomic number greater than that of europium (Eu 3+ ), seem to follow no obvious rule. For example, the complexes of Q [7] with Eu …”

mentioning

confidence: 99%

mentioning

confidence: 99%

See 2 more Smart Citations

One-Dimensional Coordination Polymers of Lanthanide Cations to Cucurbit[7]uril Built Using a Range of Tetrachloride Transition-Metal Dianion Structure Inducers

et al. 2013

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“…The coordination chemistry of alkali metal cations and their interactions with ligands have been widely studied in the past years [7][8][9][10] including the chemistry of molecular clusters [11,12] or macrocyclic compounds [13][14][15]. Many of the obtained complex compounds have potential applications in biological, inorganic, and synthetic chemistry [16,17] and in biotechnology [18].…”

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confidence: 99%

Alkali metal halogenides coordination compounds with hexamethylenetetramine

et al. 2012

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, have been synthesized and characterised by IR spectroscopy, thermogravimetry coupled with differential thermal analysis, elemental analysis and X-ray crystallography. Both the sodium compounds are isostructural in a solid state, an isostructurality is also observed between compounds containing potassium and rubidium iodides. The sodium compounds exist as dimers (dinuclear core of the complex ion is created by two sodium cations and two water molecules). The molecules of potassium and rubidium compounds are assembled to the two dimensional hybrid nets. The each potentially multifunctional ligand (the hmta) exists in the outer coordination sphere in lithium compounds, acts in a monodentate mode in sodium compounds and in bidentate-bridging modes in potassium and rubidium compounds. The lithium ions are four coordinated, and the sodium, potassium and rubidium ions are six coordinated. Thermal analyses show that the investigated compounds decompose gradually with the formation of alkali metal halides which, during the further heating, are totally removed or they undergo partial decomposition to oxides.

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