Coordination compounds of indium

Habeeb, J. J.; Said, Farouq F.; Tuck, Dennis G.

doi:10.1016/s0022-328x(00)90625-9

Cited by 35 publications

(25 citation statements)

References 19 publications

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“…The electrochemical procedures were similar to those described in earlier papers (1)(2)(3)(4)(5)(6)(7)(8). The metal to be oxidised formed the anode of a single cell containing an acetonitrile solution of either the organohalide or a quantity of concentrated aqueous hydrohalic acid, plus the neutral donor triphenylphosphine; details of the solution compositions used in the preparation of triphenylphosphine adducts are shown in Table 2.…”

Section: Electrochemical Synthesismentioning

confidence: 99%

The direct electrochemical synthesis of triphenylphosphine adducts of Group IB monohalides

Khan¹,

Oldham²,

Tuck³

1981

Can. J. Chem.

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The electrochemical oxidation of copper, silver, or gold into acetonitrile solutions of benzyl chloride or hydrogen halide plus triphenylphosphine leads to the formation of the adducts MXLn (M = Cu, Ag, Au; X = Cl, Br, I; L = Ph3P; n = 1, 1.5, 2; not all combinations). The value of n depends markedly on the mole ratio Ph3P:dissolved metal. The reaction pathway is discussed in the light of measurements of current efficiency. The results of X-ray structural studies of AuCl•L and AuClL2 are briefly reported.

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Section: Electrochemical Synthesismentioning

confidence: 99%

The direct electrochemical synthesis of triphenylphosphine adducts of Group IB monohalides

Khan¹,

Oldham²,

Tuck³

1981

Can. J. Chem.

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“…For the experiments involving a-diketonate or oxinate, the E , values were found to be ThIHacac EF = 0.18 mol F-' ThIHtfha EF = 0.19 mol F-I ThIHoxine E F = 0.22 mol F-' close to the value of 0.25 mol F-I required for an anode reaction such as which implies the Faradaic behaviour found in other metalla-diketonate electrolytic oxidations (10). As in such experiments, the formation of gas (H,) at the cathode was noted.…”

Section: Electrochemical Efficiencymentioning

confidence: 51%

“…The electrochemical syntheses followed methods described various reviews and standard texts but few in earlier publications (6)(7)(8)(9). The solution phase, typically 50 papers have appeared on the coordination , L in V O I U~~.…”

Section: Introductionmentioning

confidence: 99%

“…These experi-p r +~~~~~{~~~;~~~;~~t !~C ?, "; AXi dat i on of thorium merits represent a natural previous into bromine (2-4g) in 50 mL acetonitrile was a solution of direct electrochemical syntheses of the neutral ThBr,. Addition of diethyl ether led to the precipitation of halides of various main group and transition metals ThBr4.4CH3CN which was collected, washed with ether, and (5)(6)(7)(8)(9)(10). solution phases of^, + R,NX yield salts of dried in uaclro at room temperature.…”

Section: Introductionmentioning

confidence: 99%

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The direct electrochemical synthesis of neutral and anionic complexes of thorium(IV)

Kumar¹,

Tuck²

1982

Can. J. Chem.

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N. KUMAR and DENNIS G. TUCK. Can. J. Chem. 60,2579Chem. 60, (1982. The electrochemical oxidation of thorium into solutions of halogen (X,; X = Cl, Br) in acetonitrile yields the adducts ThX4.4CH3CN in good yield. With solutions of X, + R,NX, the products are (R,N),ThX,. Neutral chelate complexes such as Th(acac), (acac = 2,4-pentanedionate) can also be prepared in a one-step synthesis from the metal, but cationiccomplexescould not be obtained by electrochemical methods.N. KUMAR et DENNIS G. TUCK. Can. J. Chem. 60, 2579Chem. 60, (1982.L'oxydation Clectrochimique du thorium dans des solutions d'acktonitrile contenant des halogenes (X,; X = C1, Br) conduit a des adduits du type ThX4.4CH3CN avec un bon rendement. Avec des solutions de X, + R,NX, on obtient des produits du type (R,N),ThX,. On peut Cgalement preparer des chClates complexes neutres, tel Th(acac), (acac = pentane dionate-2,4), en une seule Ctape a partir du mCtal, mais on n'a pas pu obtenir les complexes cationiques par des mCthodes Clectrochimiques.[Traduit par le journal]

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“…After checking its purity using IR and ~H NMR spectra, the Schiff base was used to prepare [MnL2phen] by an electrochemical method similar to that described by Habeeb, Tuck & Waiters (1978). The electrochemical oxidation of manganese was carded out in a 100 ml 'tall-form' beaker with a solution of 0.27 g of HL (1.37 mmol), 0.121 g of 1,10-phenanthroline (phen) (6.72 mmol) and 10 mg of tetraethylammonium perchlorate in 50 ml of acetonitrile by applying a …”

Section: Methodsmentioning

confidence: 99%

Chlorobis(N-phenylsalicylideneaminato-O,N)manganese(III): a manganese Schiff-base complex derived by an electrochemical route

McAuliffe¹,

Pritchard²,

Luaces³

et al. 1993

Acta Crystallogr C

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Coordination compounds of indium

Cited by 35 publications

References 19 publications

The direct electrochemical synthesis of triphenylphosphine adducts of Group IB monohalides

The direct electrochemical synthesis of triphenylphosphine adducts of Group IB monohalides

The direct electrochemical synthesis of neutral and anionic complexes of thorium(IV)

Chlorobis(N-phenylsalicylideneaminato-O,N)manganese(III): a manganese Schiff-base complex derived by an electrochemical route

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