Coordination Compounds and Inorganics

Materazzi, Stefano

doi:10.1016/s1573-4374(08)80015-5

Cited by 2 publications

(2 citation statements)

References 230 publications

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“…In recent years, the interest and effort in the synthesis, characterisation, functionalisation, modelling, and designing of novel nanoporous materials have gained a massive insurgence ( Materazzi et al, 2008 ). This owes mostly to the fact that the properties of these materials are not only dependent on how atoms are arranged within their crystals, but also on the size and shape of their pores as well as on their specific surface area.…”

Section: Introductionmentioning

confidence: 99%

Role of Host-Guest Interaction in Understanding Polymerisation in Metal-Organic Frameworks

et al. 2021

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Metal-organic frameworks, MOFs, offer an effective template for polymerisation of polymers with precisely controlled structures within the sub-nanometre scales. However, synthetic difficulties such as monomer infiltration, detailed understanding of polymerisation mechanisms within the MOF nanochannels and the mechanism for removing the MOF template post polymerisation have prevented wide scale implementation of polymerisation in MOFs. This is partly due to the significant lack in understanding of the energetic and atomic-scale intermolecular interactions between the monomers and the MOFs. Consequently in this study, we explore the interaction of varied concentration of styrene, and 3,4-ethylenedioxythiophene (EDOT), at the surface and in the nanochannel of Zn2(1,4-ndc)2 (dabco), where 1,4-ndc = 1,4-naphthalenedicarboxylate and dabco = 1,4-diazabicyclo[2.2.2]octane. Our results showed that the interactions between monomers are stronger in the nanochannels than at the surfaces of the MOF. Moreover, the MOF-monomer interactions are strongest in the nanochannels and increase with the number of monomers. However, as the number of monomers increases, the monomers turn to bind more strongly at the surface leading to a potential agglomeration of the monomers at the surface.

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Section: Introductionmentioning

confidence: 99%

Role of Host-Guest Interaction in Understanding Polymerisation in Metal-Organic Frameworks

et al. 2021

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“…In 2008, we identified more than 500 articles after searching Web of Science, PubMed, SciDir and OVID databases using ‘isothermal AND titration AND calorimetry’ or ITC or ‘Isothermal Titration Calorimetry’ search terms. Following the format of previous annual surveys these have been classified into the following categories: References cited in the text and review articles 1–82. Protein–protein and protein–peptide interactions 83–222. Protein–small ligand or protein–drug interactions 223–321. Protein/peptide metal interactions 322–355. Protein/peptide nucleic acid interactions 356–387. Protein/peptide lipid interactions …”

Section: Introductionmentioning

confidence: 99%

Survey of the year 2008: applications of isothermal titration calorimetry

Falconer

Penkova

Jelesarov

et al. 2010

J of Molecular Recognition

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Isothermal titration calorimetry (ITC) is a fast, accurate and label-free method for measuring the thermodynamics and binding affinities of molecular associations in solution. Because the method will measure any reaction that results in a heat change, it is applicable to many different fields of research from biomolecular science, to drug design and materials engineering, and can be used to measure binding events between essentially any type of biological or chemical ligand. ITC is the only method that can directly measure binding energetics including Gibbs free energy, enthalpy, entropy and heat capacity changes. Not only binding thermodynamics but also catalytic reactions, conformational rearrangements, changes in protonation and molecular dissociations can be readily quantified by performing only a small number of ITC experiments. In this review, we highlight some of the particularly interesting reports from 2008 employing ITC, with a particular focus on protein interactions with other proteins, nucleic acids, lipids and drugs. As is tradition in these reviews we have not attempted a comprehensive analysis of all 500 papers using ITC, but emphasize those reports that particularly captured our interest and that included more thorough discussions we consider exemplify the power of the technique and might serve to inspire other users.

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Coordination Compounds and Inorganics

Cited by 2 publications

References 230 publications

Role of Host-Guest Interaction in Understanding Polymerisation in Metal-Organic Frameworks

Role of Host-Guest Interaction in Understanding Polymerisation in Metal-Organic Frameworks

Survey of the year 2008: applications of isothermal titration calorimetry

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