Coordination chemistry effects of the space-demanding solvent molecule N,N′-dimethylpropyleneurea

Abstract

Crystallographic investigations of eight homoleptic N,N’-dimethylpropyleneurea (dmpu) coordinated metal ions in solid state, [Mg(dmpu)5]I2 (1), [Ca(dmpu)6]I2 (2), [Ca(dmpu)6](ClO4)2 (3), [Ca(dmpu)6](CF3SO3)2 (4), [Sr(dmpu)6](CF3SO3)2 (5), [Ba(dmpu)6](CF3SO3)2 (6), [Sc(dmpu)6]I3 (7), and [Pr(dmpu)6](I3)2I (8),...