When studying peaks in electricity demand, we may be interested in understanding the risk of a certain large level for demand being exceeded. For example, there is potential interest in finding the probability that the electricity demand of a business or household exceeds the contractual limit. An alternative, yet in principle equivalent way, involves assessment of maximal needs for electricity over a certain period of time, like a day, a week or a season within a year. This would stem from the potential interested in quantifying the largest electricity consumption for a substation, household or business. In either case, we are trying to infer about extreme traits in electricity loads for a certain region assumed fairly homogeneous with the ultimate aim of predicting the likelihood of an extreme event which might have never been observed before. While the exact truth may be not be possible to determine, it may be possible come up with an educated guess (an estimate) and ascertain confidence margins around it. In this chapter, not only we will list and describe mainstream statistical methodology for drawing inference on extreme and rare events, but we will also endeavour to elucidate what sets the semiparametric approach apart from the classical parametric approach and how these two eventually align with one another. For details on possible approaches and related statistical methodologies we refer to [1, 2]. We hope that, through this chapter, practitioners and users of extreme value theory will be able to see how the theoretical results in Chap. 3 translate in practice and how conditions can be checked. We will be mainly concerned with semi-parametric inference for univariate extremes. This statistical methodology builds strongly on the fundamental results expounded in the previous section, most notably the theory of extended regular variation (see e.g. [3], Appendix B). Despite the numerous approaches whereby extreme values can be statistically analysed, these are generally classed into two main frameworks: methods for maxima over fixed intervals (blocks) and methods for exceedances (peaks) over high