“…We propose that transformation mechanisms of iron oxides revealed in this study are applicable to various natural and laboratory systems involving low-temperature hydrothermal fluids, which were also discussed partly in Otake et al (2007). Barnes, 1983;Zierenberg and Shanks (1983); Rona, 1984), volcanogenic massive sulfide (Callow, 1967;Westendorp et al, 1991) and oxide (Davidson, 1992;Duhig et al, 1992) deposits, magnetite skarn-deposits (Buseck, 1966;Zü rcher et al, 2001;Forster et al, 2004), Olympic Dam-type (Fe oxide-Cu-Au-Co), porphyry Cu deposits (Gow et al, 1994;Lynch and Ortega, 1997;Kolb et al, 2006), and banded iron formations (BIFs; Ewers and Morris, 1981;LaBerge et al, 1987;Pecoits et al, 2009). Some authors questioned whether redox equilibrium was attained between the iron oxides, and whether enough oxidants/reducants were present during the replacement of magnetite to hematite/ hematite to magnetite.…”