The properties of piezoelectric materials due to the effect of electrical, mechanical, thermal, radiation, and chemical parameters are systematized. On the basis of Maxwell's relations (obtained from expressions for thermodynamic functions) and the application of the system analysis methodology, it made it possible to develop an analytical model of the relationship between the parameters and properties of piezoelectrics in the form of a system of equations. The results of the metrological analysis of an analytical model, which made it possible to identify the sources of additional errors in the measurement of parameters, to derive formulas for their calculation, which in turn contributes to an increase in the accuracy of measurements of the piezoelectrics parameters and products based on them, are presented.