“…For example, the 4-, 6-, and 8-fold symmetries of the individual voxel bonds ,,,– result in diamond, simple cubic, and body-centered cubic frameworks, providing different 3D scaffolds to place NCs. By adding a bond identity to the valence when using different sequences, or a composition of a number of sequences for different directional bonds, a higher degree of structural diversity is achieved. ,, This approach permits (i) coordinating different types of frames, empty or with cargo, to create increasingly complex organizations, ,, and (ii) establishing an inverse design of lattices through the selection of bonds with different identities for a set of voxels. However, the requirements of the bond encoding and their energy distribution for an effective assembly process are unknown.…”