“…The reaction kinetics can be affected by the numbers of initial nucleations through altering the reaction parameters, so as to cause the oriented growth of crystal structure sorts and further influence the properties of materials, such as the size, shape, structure, and purity of these materials. [ 29 ] Up to now, typical structures of Bi 2 S 3 (such as nanowires, [ 30,31 ] nanorods, [ 32–35 ] nanotubes, [ 36–38 ] nanobelts, [ 39 ] nanowhiskers, [ 40 ] nanoflowers, [ 41–43 ] snowflake‐like, [ 44 ] and urchin‐like nanospheres [ 45 ] ) have been successfully gained via the hydrothermal, [ 46–59 ] solvothermal, [ 60–72 ] ionic liquid‐assisted, [ 73–78 ] and microwave‐assisted processes. [ 79–84 ] The structural diversity of Bi 2 S 3 makes it increasingly attractive highlights, owing to the essential properties when exploring its further applicability ( Figure ).…”