“…We find a linear relation between the externally applied charging potential and the charging state of the PEI Ultem 1000 films. A similar linear relationship has been reported for glass, silicon oxide, silicon oxynitride, inorganic heterostructure materials, as well other polymeric materials such as cycloolefin copolymer, polycarbonate, poly(vinyl acetate) poly(methyl methacrylate), and polyacrylamide. ,, The PEI films could be charged already with V charge = 1 V, while for various other polymeric materials thresholds >1 V have been reported. , Here, the highest charging voltage has been limited to 10 V due to the instrumental limitations. For this V charge , we find a relative surface potential of V CPD = 1.2 V. For the charging process, several mechanisms have been proposed, such as ion adsorption/injection from a water layer on the sample, ,, a process that is similar to liquid contact charging, , and field electron emission enhanced by thermionic emission. , For comparison, the analogous procedure has been tested also for an inorganic layer, namely, SiO 2 on a doped silicon wafer.…”