structure and lattice defects, whereas magnetic phenomena derive from spintronic characteristics and dynamics of charge carriers. [1,4-6] To be sure, coupling between optical and magnetic effects is well known through the Kerr and Faraday effects. [7,8] Recent advances of light-induced magnetization and light-controlled spin current have drawn extensive interest for promising applications of optical memory devices. [9,10] Light-controlled magnetism has been observed principally in magnetic materials. [11-14] It is also of interest for non-magnetic materials, for which incident photons tend to control the spin polarization, possibly causing a modulation in magnetoresistance (MR). [15,16] A worthwhile goal is to utilize photon energy to gain control of magnetic states, thus utilizing the storage feature of magnetic phenomena to achieve memory of optical signals. This strategy is expected to lead to optospintronic devices, [17] by combining the advantages of optical and magnetic characteristics. Compared with the traditional ferromagnetic memory devices, the direct storage of optical signals in optical memory devices is promising for applications in existing network systems, [18] especially when considering that the information transmission is almost always performed through optical fibers. Without extra signal conversions, the optical memory devices may decrease the loss of optical signals and enhance the efficiency of information transmission. Although much research has been reported on the optical control of spin current in non-magnetic materials, [15-17,19] few studies investigated the light-induced sign switching between positive magnetoresistance (PMR) and negative magnetoresistance (NMR). PMR occurs when electrical resistance increases as an applied external magnetic field increases; NMR is an opposite phenomenon-a decreasing resistance as magnetic field increases. NMR is usually caused by spindependent scattering or a magnetic-field-induced phase transition. [2,3] Generally, most materials show PMR effect due to Lorentz force. [20] In non-magnetic materials, the NMR effect is very rare and often depends on specific physical mechanisms, including strain effect, electrical gating, chiral anomaly in Weyl semimetals, and so on. [21-23] Exploring the light-induced NMR effect in non-magnetic systems may advance a physical understanding of optospintronics and provide a new route toward optical memory devices based on MR switching.