Controlled copolymerization of acrylonitrile with methyl acrylate and dimethyl itaconate via ARGET ATRP mechanism

Гришин, И. Д.; Stakhi, S. A.; Kurochkina, D. Yu.; Гришин, Д. Ф.

doi:10.1007/s10965-018-1653-9

Cited by 15 publications

(7 citation statements)

References 27 publications

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“…The V CA of the HMCF increases linearly and gradually as the 1-octadecene dosage increases, which is consistent with the characteristics of the ARGET-ATRP mechanism. 32 Meanwhile, the V RCA value initially climbs but subsequently decreases by a few degrees, with the optimum D r value of 5.7% being attained with a monomer dosage of 2.4 g. These results indicate that a continuous grafted-copolymerization reaction between the esterification cellulose and monomer causes not only a slight increase in the number of grafted sites on the cotton fabric but also contributes to the homopolymerization of the monomer when there is sufficient monomer in the ARGET-ATRP reaction system.…”

Section: Resultsmentioning

confidence: 99%

Preparation of hydrophobically modified cotton filter fabric with high hydrophobic stability using ARGET-ATRP mechanism

Chen³

et al. 2019

RSC Adv.

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Section: Resultsmentioning

confidence: 99%

Preparation of hydrophobically modified cotton filter fabric with high hydrophobic stability using ARGET-ATRP mechanism

Chen³

et al. 2019

RSC Adv.

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“…[ 205 ] N ‐phenylitaconimide was polymerized by ICAR ATRP catalyzed by FeBr 3 , then the polymer was used as a macroinitiator to form a copolymer with styrene, [ 206 ] and homopolymers of dimethyl itaconate [ 207 ] and their copolymers with acrylonitrile by ARGET ATRP. [ 208 ] Thus, biomass‐derived monomers were effectively paired with greener synthetic conditions, such as low catalyst loadings and benign Fe‐based catalysts.…”

Section: The 12 Principles Of Green Chemistry and Their Implementatio...mentioning

confidence: 99%

Toward Green Atom Transfer Radical Polymerization: Current Status and Future Challenges

et al. 2022

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Dedicated to Professor Klaus Muellen on the occasion of his 75th birthdayReversible-deactivation radical polymerizations (RDRPs) have revolutionized synthetic polymer chemistry. Nowadays, RDRPs facilitate design and preparation of materials with controlled architecture, composition, and functionality. Atom transfer radical polymerization (ATRP) has evolved beyond traditional polymer field, enabling synthesis of organic-inorganic hybrids, bioconjugates, advanced polymers for electronics, energy, and environmentally relevant polymeric materials for broad applications in various fields. This review focuses on the relation between ATRP technology and the 12 principles of green chemistry, which are paramount guidelines in sustainable research and implementation. The green features of ATRP are presented, discussing the environmental and/or health issues and the challenges that remain to be overcome. Key discoveries and recent developments in green ATRP are highlighted, while providing a perspective for future opportunities in this area.

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“…[ 141 ] Similarly, terpolymers of acrylonitrile, MMA and DMI were obtained by AGET‐ATRP using CuBr/tris(2‐pyridylmethyl)amine/CCl 4 with glucose or ascorbic acid as reducing agents. [ 142 ] Under optimized conditions, a M n of 72600 and a PDI of 1.33 were obtained. [ 142 ] Further, ATRP was used to functionalize the surface of fly ash with poly(itaconic acid‐co‐acrylic acid) chains.…”

Section: Controlled Radical Polymerization Of Itaconic Acid and Its Dmentioning

confidence: 99%

“…[ 142 ] Under optimized conditions, a M n of 72600 and a PDI of 1.33 were obtained. [ 142 ] Further, ATRP was used to functionalize the surface of fly ash with poly(itaconic acid‐co‐acrylic acid) chains. [ 143 ] When used as a concrete additive, these composites increased the compressive strength of the modified concrete compared to untreated fly ash.…”

Section: Controlled Radical Polymerization Of Itaconic Acid and Its Dmentioning

confidence: 99%

Progress in the Free and Controlled Radical Homo‐ and Co‐Polymerization of Itaconic Acid Derivatives: Toward Functional Polymers with Controlled Molar Mass Distribution and Architecture

Sollka

Lienkamp

2020

Macromol. Rapid Commun.

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Polymeric derivatives of itaconic acid are becoming increasingly more interesting for research and industry because itaconic acid is accessible from renewable resources. In spite of the structural similarity of poly(itaconic acid derivatives) to poly(methacrylates), they are much less reactive, homopolymerize only sluggishly by free radical polymerization (FRP), and are often obtained with low molar masses and conversions. This has so far limited their use. The reasons for the low reactivity of itaconic acid derivatives (including itaconimides, diitaconates, and diitaconamides) are combined steric and electronic effects, as demonstrated by the body of literature on the FRP homopolymerization kinetics of these monomers which is summarized herein. These problems can be solved to a large extent by using controlled radical polymerization (CRP) techniques, notably atom transfer radical polymerization (ATRP) and reversible addition and fragmentation chain transfer radical polymerization (RAFT). By optimizing the reaction conditions for the ATRP and RAFT of itaconic acid derivatives, in particular the reaction temperature, linear relations between molar mass and conversion are obtained in many cases, and homopolymers with high molar masses and reasonably narrow polydispersity indices become accessible. This review presents the state‐of‐the‐art FRP and CRP of itaconic acid derivatives, and highlights functional polymers obtained by these methods.

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Controlled copolymerization of acrylonitrile with methyl acrylate and dimethyl itaconate via ARGET ATRP mechanism

Cited by 15 publications

References 27 publications

Preparation of hydrophobically modified cotton filter fabric with high hydrophobic stability using ARGET-ATRP mechanism

Preparation of hydrophobically modified cotton filter fabric with high hydrophobic stability using ARGET-ATRP mechanism

Toward Green Atom Transfer Radical Polymerization: Current Status and Future Challenges

Progress in the Free and Controlled Radical Homo‐ and Co‐Polymerization of Itaconic Acid Derivatives: Toward Functional Polymers with Controlled Molar Mass Distribution and Architecture

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