Controllable Pyridine N-Oxidation–Nucleophilic Dechlorination Process for Enhanced Dechlorination of Chloropyridines: The Cooperation of HCO4– and HO2–
Ying Chen,
Lei Tian,
Wen Liu
et al.
Abstract:Dechlorination of chloropyridines can eliminate their detrimental environmental effects. However, traditional dechlorination technology cannot efficiently break the C−Cl bond of chloropyridines, which is restricted by the uncontrollable nonselective species. Hence, we propose the carbonate species-activated hydrogen peroxide (carbonate species/H 2 O 2 ) process wherein the selective oxidant (peroxymonocarbonate ion, HCO 4 −) and selective reductant (hydroperoxide anion, HO 2 − ) controllably coexist by manipul… Show more
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