1995
DOI: 10.1021/ic00105a017
|View full text |Cite
|
Sign up to set email alerts
|

Control of the Bridgehead Donor Atom in the Tripodal Ligand over Oxidative Addition of Au(PPh3)+ to [X(CH2CH2PPh2)3RhH] (X = N, P). X-ray Diffraction and Multinuclear (103Rh, 31P, 1H) NMR Studies

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
2
1
1

Citation Types

1
13
0

Year Published

1997
1997
2021
2021

Publication Types

Select...
5
2

Relationship

0
7

Authors

Journals

citations
Cited by 26 publications
(14 citation statements)
references
References 11 publications
(13 reference statements)
1
13
0
Order By: Relevance
“…All complexes of PP 3 involving metal-metal bonds reported so far (Scheme 2) involve this bonding mode. [2][3][4][5] We report here on the facile formation of dinuclear metalmetal bonded M 2 (µ-PP 3 -P,PЈ : PЉ,Pٞ) fragments depicted in Scheme 1.…”
Section: Introductionmentioning
confidence: 99%
“…All complexes of PP 3 involving metal-metal bonds reported so far (Scheme 2) involve this bonding mode. [2][3][4][5] We report here on the facile formation of dinuclear metalmetal bonded M 2 (µ-PP 3 -P,PЈ : PЉ,Pٞ) fragments depicted in Scheme 1.…”
Section: Introductionmentioning
confidence: 99%
“…In this case, stable complexes of type II have been isolated and characterized in numerous occasions. [11][12][13][14][15][16][17][18][19][20][21][22][23][24] Whenever these adducts are not stable, the † Current address: Laboratoire de Synthe `se et d'Electrosynthe `se Organometallique, Faculte ´des Sciences "Gabriel", 6 Boulevard Gabriel, 21100 Dijon, France.…”
Section: Introductionmentioning
confidence: 99%
“…As expected, the rhodium center in the two structures adopts a piano‐stool conformation. Compound 3 b exhibits a Rh‐Au bond distance of 2.593(1) Å, comparable to the only other example of a bimetallic Rh/Au unsupported MOLP of this kind [26] . This value is shortened by around 0.2 Å with respect to the sum of their covalent radii (2.78 Å), [27] thus providing support for the existence of a dative Rh→Au bond.…”
Section: Figurementioning
confidence: 59%
“…Compound 3 b exhibits a Rh-Au bond distance of 2.593(1) , comparable to the only other example of a bimetallic Rh/Au unsupported MOLP of this kind. [26] This value is shortened by around 0.2 with respect to the sum of their covalent radii (2.78 ), [27] thus providing support for the existence of a dative Rh!Au bond. Similarly, the calculated formal shortness ratio (FSR), [28] defined as the ratio between the MÀM length and the sum of metallic radii, exactly accounts for 1.00.…”
mentioning
confidence: 90%