Control of Substrates Beyond the Catalyst Active Site

Efficacy analysis of compartmentalization for ambient CH4 activation mediated by a RhII metalloradical in a nanowire array electrode

“…20 The synergy between nanomaterials and organometallic chemistry warrants a new catalytic route of CH 4 functionalization, while additional studies are needed to understand the underlying mechanism and quantitatively evaluate the efficacy of the strategy that interfaces nanowires with organometallics. 23 Here we report our analysis of the above-mentioned CH 4 -to-CH 3 OH catalysis in the context of a compartmentalized cascade. We translated the reported catalytic system into a theoretical model that estimates the numerical value of g. Electron paramagnetic resonance (EPR) spectroscopy with a spin-trap agent, along with other characterization experiments, unraveled that the predominant ROS present in the system is a superoxide and illustrated its role in CH 3 OH formation.…”

“… 20 The synergy between nanomaterials and organometallic chemistry warrants a new catalytic route of CH 4 functionalization, while additional studies are needed to understand the underlying mechanism and quantitatively evaluate the efficacy of the strategy that interfaces nanowires with organometallics. 23 …”

Efficacy Analysis of Compartmentalization for Ambient CH4 Activation Mediated by RhII Metalloradical in Nanowire Array Electrode

“…20 The synergy between nanomaterials and organometallic chemistry warrants a new catalytic route of CH4 functionalization, while additional study is needed to understand the underlying mechanism and quantitatively evaluate the efficacy of the strategy that interface nanowires with organometallics. 23 Here we report our analysis of the above-mentioned CH4-to-CH3OH catalysis in the context of compartmentalized cascade. We translated the reported catalytic system into a theoretical model that estimates the numerical value of .…”