Contribution to the coordination chemistry of osmium

Spacu, P.; Gheorghiu, Constanta

doi:10.1016/0022-5088(69)90130-1

Cited by 7 publications

(3 citation statements)

References 11 publications

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“…Complexes of 1,1-dimethylbiguanide, namely Cu(II) (Viossat et al, 1995;Zhu et al, 2002), Rh(III) (Spacu & Gheorghiu, 1968), Ir(III) (Gheorghiu, 1969), Os(II) and Os(III) (Spacu & Gheorghiu, 1969), Tc(V) and Re(V) complexes (Marchi et al, 1999) have been studied.…”

Section: Related Literaturementioning

confidence: 99%

1,1-Dimethylbiguanidium(2+) dinitrate

2011

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In the crystal structure of the title compound, C4H13N5 2+·2NO3 −, the main intermolecular interactions are the N—H⋯O hydrogen bonds between the cationic amino groups and the O atoms of the nitrate ions. All amino H atoms and nitrate O atoms are involved in the three-dimensional hydrogen-bond network. There are two graph-set motifs R 2 2(8), which include the amino groups connected to the N atoms in the biguanide 3-, 4- and 5-positions, and the O atoms of a nitrate ion. They are extended along the a axis. An O atom of the second nitrate ion is involved in a graph-set motif C(4) that is a part of a helix-like N—H⋯O⋯H—N—H⋯O⋯ chain oriented along the b axis. There are also two weak C—H⋯O interactions in the crystal structure.

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Section: Related Literaturementioning

confidence: 99%

1,1-Dimethylbiguanidium(2+) dinitrate

2011

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“…Metformin coordinates to the silicon atom in a neutral as well as a deprotonated form to yield two different types of complexes [9]. Also, complexes of Metformin with Rh(III) [10], Ir(III) [11], Os(II) and Os(III) [12], Tc(V) and Re(V) complexes [13] have been studied.…”

Section: Introductionmentioning

confidence: 99%

Synthesis, spectroscopic and antimicrobial studies of La(III), Ce(III), Sm(III) and Y(III) Metformin HCl chelates

Refat

Al-Azab

Al-Maydama

et al. 2015

Spectrochimica Acta Part A: Molecular and Biomolecular Spectros

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“…Metformin coordinates to the silicon atom in a neutral as well as a deprotonated form to yield two different types of complexes [2]. Many metformin complexes of Rh(III) [3], Ir(III) [4], Os(II) and Os(III) [5], Tc(V) and Re(V) complexes have been studied. Metformin with 2,6-pyridinedicarboxylic acid formed promising complex with Pd(II) as an insulin-mimic compound [6].…”

Section: Introductionmentioning

confidence: 99%