Contribution À L'Étude des Réactions de Combinaison des Radicaux Alcoyle Tertiaires en Phase Solide

Abstract

Disproportionation/combination ratios of self-reactinq t-alkyl radicals are estimated in solid phase at low temperature. The low temperature solid state limit was estimated to be 7-25, this value is considerably lower than ratios of the literature (100 to 500) and is compatible with the FISCHER limit in liquid state. In the present work, the ratios are determined by product analysis from the gamma radiolysis of isobutane.