2022
DOI: 10.1038/s41560-022-00993-z
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Continuous transition from double-layer to Faradaic charge storage in confined electrolytes

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Cited by 156 publications
(138 citation statements)
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“…S7 and S8 †). 80 The obtained reduction and oxidation peaks from cyclic voltammetry agree with the galvanostatic discharge and charge proles tested at different specic currents in a voltage range between 0.1 and 2.0 V vs. Na + /Na as shown in Fig. 6A and B.…”
Section: Electrochemical Characterizationsupporting
confidence: 75%
“…S7 and S8 †). 80 The obtained reduction and oxidation peaks from cyclic voltammetry agree with the galvanostatic discharge and charge proles tested at different specic currents in a voltage range between 0.1 and 2.0 V vs. Na + /Na as shown in Fig. 6A and B.…”
Section: Electrochemical Characterizationsupporting
confidence: 75%
“…The study of Li plating/stripping kinetics on the investigated substrates was carried out through electrochemical approaches, where the powders of HMOs were coated on Cu foils to form the working electrodes [Supplementary Figure 3]. The voltage profiles of the initial Li electroplating were first assessed, where the Li nucleation overpotential can be revealed as the difference between the voltage dip and plateau [26] . At a current density of 1 mA cm -2 , a high Li nucleation overpotential of ~180 mV was achieved on bare Cu, which can result in unevenly distributed Li nuclei, followed by dendrite growth [Figure 3A].…”
Section: Resultsmentioning
confidence: 99%
“…There is debate about the fundamental nature of these responses, [52,[54][55][56][57][58][59][60][61] including rigorous theoretical arguments that the first camp is attributed principally to EDLC [60] and a separate suggestion of a continuum between Faradaic and EDLC. [62] If indeed charge storage were dominated by EDLC, then the term pseudocapacitance [60] would be inaccurate. T-Nb 2 O 5 was the first material described as exhibiting intercalation pseudocapacitance.…”
Section: Rapid Intercalation Materials and Pseudocapacitancementioning
confidence: 99%