Continuous Coulometric Analysis Using Working Electrode of Predetermined Potential

Eckfeldt, Edgar L.

doi:10.1021/ac60153a014

Cited by 20 publications

(8 citation statements)

References 4 publications

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“…: ELECTROCHEMICAL SCIENCE AND TECHNOLOGY December 1976 the deposition of each metal proceeds independently of the other (that is, i = j) with the reversible rate expression [9] ci o Although more complicated rate equations could be used to suit special circumstances, let us assume that J. EIectrochem.…”

Section: Multiple Metal Depositionmentioning

confidence: 99%

“…[9], the quantity ~ is the potential with respect to the rest potential of the ion of the most noble metal, while ~#ri is the rest potential of the ion of the most noble metal with respect to species i. [9], the quantity ~ is the potential with respect to the rest potential of the ion of the most noble metal, while ~#ri is the rest potential of the ion of the most noble metal with respect to species i.…”

Section: Rtmentioning

confidence: 99%

“…This effect has been well documented for the lead-acid system (6)(7)(8)(9)(10)(11) and is particularly damaging not only for the effects on mechanical integrity but also for its contribution to internal resistance, a factor which limits battery performance. Most notable of these is the classical problem of localized attack of segregated materials such as the eutectic structure or intermetallic compounds.…”

Section: R Imentioning

confidence: 99%

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Analysis of Multiple Reaction Sequences in Flow‐Through Porous Electrodes

Alkire¹,

Gould

1976

J. Electrochem. Soc.

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The role of multiple reactions in flow-through porous electrodes has been investigated theoretically. The reaction sequences studied include simultaneous deposition of several metals, deposition o~ a metal in tr_e presence of a redox system, and an ECE sequence which is characteristic of many electro-organic synthesis reactions. The model accounts for mass transport, multiple charge transfer reactions, homogeneous chemical reactions, ohmic and geometric parameters. Results are compiled in a series of graphs which elucidate electrode behavior over a wide region of parameter space.

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Section: Multiple Metal Depositionmentioning

confidence: 99%

Section: Rtmentioning

confidence: 99%

Section: R Imentioning

confidence: 99%

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Analysis of Multiple Reaction Sequences in Flow‐Through Porous Electrodes

Alkire¹,

Gould

1976

J. Electrochem. Soc.

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“…or derivative coulometry at predetermined electrode potential and the interesting possibilities of this technique for measuring electrooxidizable or reducible substances have been' reported (3). The present paper describes progress in applying the technique to the determination of dissolved oxygen in water.…”

Section: Continuousmentioning

confidence: 96%

“…The equation takes into account the oxygen which both entered and left flask E at the time the air-saturated water was admitted. Integration of Equation 2 from 0 to C, and 0 to Vi gives the equation used C = X (l -e~ ( 3) where were sufficiently small to introduce only a negligible decrease in oxygen concentration of the solution in flask E.…”

Section: Continuousmentioning

confidence: 99%