Brassica Campestis L. was cultivated in the soil at the laboratory. The red edge, the visual spectrum and the near-infrared spectrum of Brassica Campestis L. leaf were used to explore the spectral response of Brassica Campestis L. leaf to the copper stress. As the Cu content in the soil gets increased, the copper level in Brassica Campestris L. leaf would be increased, and the chlorophyll level in Brassica Campestris L. leaf would be decreased. As a result, the visual spectral reflectance (A 1 ) of Brassica Campestris L. leaf is increased, and the blue-shift (moving towards the shorter waveband) degree (S) of the red edge (the ascending region of the reflectivity at 680-740 nm) gets increased. However, the near-infrared spectral reflectance (A 2 ) decreases. With the correlation coefficient R 2 more than 0.95, these parameters of A 1 , A 2 and S can be perfectly used to simulate and predict the copper level in Brassica Campestris L. leaf. red edge position, chlorophyll, plant spectrum, plant indicatorCopper pollution to the ecosystem has drawn worldwide attention [1,2] . To investigate and rehabilitate the polluted environment by the heavy metals, it is very critical to monitor and identify the polluted objects. The traditional chemical analysis is limited by scope, cost, time and labor. The vegetation-monitoring method of using the remote sensing technology is dynamic, much faster and able to provide a broader view and much more information [3,4] . This technique is becoming one of the significant methods for exploiting resource and preventing environmental pollution.As a dominant part of the terrestrial ecosystem, the vegetation has a direct impact on the holistic ecosystem. The vegetation may become an important index [5,6] to reflect the ecological pollution. When a plant is polluted by heavy metals, its leaf spectrum would be characteristically changed [7] . More and more researchers are engaged in the plant spectral response to the soil pollution and make much progress in the response mechanism [8][9][10][11] . However, there is no reported