2020
DOI: 10.1021/acs.jpclett.0c00788
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Contact Time of a Bouncing Nanodroplet

Abstract: We study the bouncing dynamics of nanodroplets on superhydrophobic surfaces. We show that there are three velocity regimes with different scaling laws of the contact time, τ. Although τ remains constant over a wide velocity range, as seen for macroscale bouncing, we demonstrate that viscosity plays an essential role in nanodroplet bouncing even for low-viscosity fluids. We propose a new scaling τ ∼ (ρμR 0 4/γ2)1/3 = (R 0/v 0)We 2/3 Re –1/3 to characterize the viscosity effect, which agrees well with the simula… Show more

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Cited by 59 publications
(31 citation statements)
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References 43 publications
(93 reference statements)
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“…As shown in figure 3(a), the droplet bounces off the surface at 60 ps for D 0 = 8 nm, 85 ps for D 0 = 10 nm and 135 ps for D 0 = 14 nm. Xie et al (2020) investigated the contact time of nanodroplets on superhydrophobic surfaces. These authors noted that, unlike millimetre-sized droplets, the effects of liquid viscosity cannot be ignored for nanodroplets in a high-Weber-number range even for low-viscosity fluids; therefore, they developed further a new scaling law of contact time, expressed as τ c ∼ τ c,h = (D 0 /V 0 )We 2/3 Re −1/3 , where τ c,h is a characteristic time scale of bouncing nanodroplets at high velocities.…”
Section: Resultsmentioning
confidence: 99%
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“…As shown in figure 3(a), the droplet bounces off the surface at 60 ps for D 0 = 8 nm, 85 ps for D 0 = 10 nm and 135 ps for D 0 = 14 nm. Xie et al (2020) investigated the contact time of nanodroplets on superhydrophobic surfaces. These authors noted that, unlike millimetre-sized droplets, the effects of liquid viscosity cannot be ignored for nanodroplets in a high-Weber-number range even for low-viscosity fluids; therefore, they developed further a new scaling law of contact time, expressed as τ c ∼ τ c,h = (D 0 /V 0 )We 2/3 Re −1/3 , where τ c,h is a characteristic time scale of bouncing nanodroplets at high velocities.…”
Section: Resultsmentioning
confidence: 99%
“…Because of the increased viscosity effect, the methods based on the energy balance between kinetic energy and surface energy (Laan et al 2014) or those based on the force balance between inertial force and capillary force (Clanet et al 2004) fail to derive the scaling law of β max for impacting nanodroplets at high velocities. Inspired by the scaling law of contact time by Xie et al (2020), the data of β/β max for the three nanodroplets in the high-Weber-number range are replotted in figure 3(b) using t/τ c,h as the abscissa. Interestingly, all the data collapse onto a single curve, indicating that there is a universal function β/β max = f (t/τ c,h ).…”
Section: Resultsmentioning
confidence: 99%
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“…Molecular dynamics (MD) simulations provide a powerful tool to probe the dynamical behaviors of nanodroplets on an atomic scale. The mechanisms of spreading, break-up, bouncing, and other behaviors of nanodroplets are discussed via MD [15][16][17][18][19]. Chen et al simulated polymer nanodroplets impinging on a solid surface and found that the viscous dissipation of water nanodroplets stemmed from the velocity gradients in both the impinging and spreading directions [20].…”
Section: Introductionmentioning
confidence: 99%