Construction of xylose assimilating yeast hybrids Through genome shuffling

Devi, J; Kishore, N. Sai

doi:10.22376/ijpbs.2017.8.3.b873-881

Cited by 2 publications

(1 citation statement)

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“…Schiff base ligand H 2 L was synthesized according to the previous report with a little change. [26,27] To a solution of 1 g (4.97 mmol) of 5-bromosalicylaldehyde in 10 mL of absolute ethanol in a 50 mL three-necked flask fitted with a condenser was slowly a solution of 0.46 g (2.49 mmol) of 2,2'-(ethylenedioxy)bis(ethylamine) in 15 mL of absolute ethanol. This mixture was heated to 60 °C with stirring and under a nitrogen atmosphere for 2 h until it turned yellow color, indicating that the Schiff base was formed.…”

Section: Synthesis Of the Schiff Base Ligand (H 2 L)mentioning

confidence: 99%

Synthesis, XRD/HSA‐Interactions, QTAIM Analysis, Optical and Nonlinear Optical Responses Studies of Cu(II) Complex with the Schiff Base Ligand Derived from 5‐Bromosalicylaldehyde

Lamiri,

Djaafer‐Moussa,

Merabet

et al. 2023

ChemistrySelect

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In this study, we efficiently synthesized a new Schiff base ligand (H2L) along with its mononuclear complex Cu(II) (1). The chemical structures of these compounds were rigorously determined using various analytical techniques, including UV‐ Vis., FT‐IR, 1H NMR, 13 C NMR CHN elemental analysis, single crystal X‐ray diffraction, and quantum calculations. The X‐ray diffraction analysis of the complex revealed the presence of intermolecular interactions characterized by C−H…Br hydrogen bonds, leading to the formation of 2D layers. We conducted a systematic investigation of these intermolecular interactions using HS and QTAIM analysis. Additionally, we affected a comprehensive analysis of H2L, 1, and 2, focusing on their structural, electronic, and optical properties using DFT and TD‐DFT calculations in gas and solvent. The computed parameters closely matched the experimental data, demonstrating good agreement. Reactivity parameters indicated that complex 2 exhibited lower hardness (~1.7 eV) compared to 1 (~1.8 eV) and H2L (~4.4 eV). NLO analysis revealed substantial α and β values for compound 2 in both static and dynamic regimes. Notably, the β values of the title complexes increased with higher solvent polarity. In summary, our investigation highlights the potential of the title complexes as promising candidates for second‐order nonlinear optical materials.

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Section: Synthesis Of the Schiff Base Ligand (H 2 L)mentioning

confidence: 99%