Construction of Ultrathin BiVO₄‐Au‐Cu₂O Nanosheets with Multiple Charge Transfer Paths for Effective Visible‐Light‐Driven Photocatalytic Degradation of Tetracycline

Abstract

In this study, unique BiVO4‐Au‐Cu2O nanosheets (NSs) are well designed and multiple charge transfer paths are consequently constructed. The X‐ray photoelectron spectroscopy measurement during a light off‐on‐off cycle and redox capability tests of the photo‐generated charge carriers confirmed the formation of Z‐scheme heterojunction, which can facilitate the charge carrier separation and transfer and maintain the original strong redox potentials of the respective component in the heterojunction. The ultrathin 2D structure of the BiVO4 NSs provided sufficient surface area for the photocatalytic reaction. The local surface plasmon resonance (LSPR) effect of the electron mediator, Au NPs, enhanced the light absorption and promoted the excitation of hot electrons. The multiple charge transfer paths effectively promoted the separation and transfer of the charge carrier. The synergism of the abovementioned properties endowed the BiVO4‐Au‐Cu2O NSs with satisfactory photocatalytic activity in the degradation of tetracycline (Tc) with a removal rate of ≈80% within 30 min under visible light irradiation. The degradation products during the photocatalysis are confirmed by using ultra‐high performance liquid chromatography‐mass spectrometry and the plausible degradation pathways of Tc are consequently proposed. This work paves a strategy for developing highly efficient visible‐light‐driven photocatalysts with multiple charge transfer paths for removing organic contaminants in water.