Construction of Poly(butylene succinate)-Grafted Graphene Bionanocomposites: Intercalation Structure, Synergistic Thermal–Oxidative Stabilization Effect, and Hydrolytic Behavior
Longkang Di,
Wuyou Wang,
Zhengwei Xie
et al.
Abstract:Poly(butylene
succinate) (PBS) is considered a promising biodegradable
material, whereas poor mechanical/thermal properties and low hydrolysis
rate restrict its further application. Herein, 1,4-butanediol (BDO)
was chemically grafted onto the graphene oxide (GO) surface by the
coupling effect of diisocyanate [e.g., 4,4′-diphenylmethane
diisocyanate (MDI), toluene diisocyanate (TDI), and hexamethylene
diisocyanate (HDI)], and the corresponding bionanocomposites were
prepared via in situ polymerization. By compa… Show more
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