Construction of crystalline cadmium complex based on 1,4,5,8‐naphthalene diimide derivative and photocatalytic degradation about organic dyes

Abstract

The complex [Cd(PDNDI)]·DMF (Cd‐PDNDI) (H2PDNDI = N‐(4‐pyridine)‐4,5‐dicarboxy‐1,8‐naphthalene dicarboxyimide) was synthesized by the reaction of N,N′‐di(4‐pyridyl)‐1,4,5,8‐naphthalene diimide (DPNDI) and Cd(NO3)2·4H2O. It was characterized by elemental analysis, infrared spectroscopy, ultraviolet–visible (UV‐vis) spectroscopy, powder X‐ray diffraction (PXRD), single crystal X‐ray diffraction, and thermogravimetric analysis. Structural analysis shows that the Cd‐PDNDI has a self‐assembled 3D network structure with the rtl type topology. It is worth mentioning that the composition of the ligand is different from the initial raw material used in this molecular structure. This may be because the ligand undergoes an in situ hydrolysis reaction in the reaction system and becomes an NDI carboxylic acid derivative, which continues to join coordination reaction with the metal ion. In addition, the Cd‐PDNDI has an excellent photocatalytic effect on malachite green (MG) among the six dyes, which shows that the Cd‐PDNDI could be used as a photocatalytic material for the degradation of dyes.

Glycols in the Synthesis of Zinc-Anilato Coordination Polymers

“…MOFs have an extensive set of properties that ensure their potential application in various fields of both fundamental and applied science. Materials based on coordination polymers can be used as gas adsorbents [2][3][4], electrochemical or photophysical sensors [5], as well as luminescent [6,7], photocatalytic [8,9], electrically conductive [10,11], and magnetic [12,13] materials. Metal-organic redox-active coordination polymers represent a particular class of derivative [14][15][16][17].…”

Developing visible light responsive BN/NTCDA heterojunctions with a good degradation performance for tetracycline

“…46,47 Functional group modification improves the electron migration ability of NDI, which can form NDI-MOF with metal elements or form a heterojunction with other semiconductors to improve its photocatalytic activity. 48,49 Liu et al 50 used L-complexine to modify NTCDA and self-assembled it with TiO 2 to form a heterojunction photocatalyst. The photodegradation of atenolol by the composites under visible light irradiation is 4.98 times higher than that of TiO 2 .…”