Construction of covalent-integrated MOFs@COFs composite material for efficient synergistic adsorption and degradation of pollutants

Zr- and Ti-based metal–organic frameworks: synthesis, structures and catalytic applications

“…In all samples tested, NM-125(Ti) 0.4 @TpTta-COF was able to adsorb and degrade 100 ppm BPA in ten minutes. 165 MOF catalysts can not only destroy organic pollutants, but also be widely used in several organic reactions. The single crystal Ti-MOF (DGIST-1) with an infinite Ti-oxo chain could oxidize benzyl alcohol to produce benzaldehyde under visible light irradiation, and the conversion rate of benzyl alcohol catalysed by DGIST-1 reached 93% without the assistance of a cocatalyst.…”

Fast charge transfer kinetics in an inorganic–organic S-scheme heterojunction photocatalyst for cooperative hydrogen evolution and furfuryl alcohol upgrading

“…The phenomenon explains that the photogenerated electrons would migrate from the Tp-Tta COF to ZnIn 2 S 4 driven by the IEF in the ZnIn 2 S 4 /Tp-Tta COF composite when the light turns on. 36,37 The charge transfer pathway derived from the binding energy changes in the ISI XPS spectra provides strong evidence for the S-scheme heterojunction mechanism of the ZT-5 photocatalyst. 38 Beneting from the S-scheme pathway of charge transfer in ZT-5, the photogenerated electrons in the highest level of the conduction band (CB) of ZnIn 2 S 4 , and holes in the lowest level of the valence band (VB) of the Tp-Tta COF with excellent redox potentials can be retained, conducive to subsequent efficient H 2 evolution and furfuryl alcohol oxidation.…”

“…The phenomenon explains that the photogenerated electrons would migrate from the Tp-Tta COF to ZnIn 2 S 4 driven by the IEF in the ZnIn 2 S 4 /Tp-Tta COF composite when the light turns on. 36,37…”

A hybrid deep learning framework driven by data and reaction mechanism for predicting sustainable glycolic acid production performance

“…7 The singularly inappropriate approach to plastic solid waste directly contributes to a surge in CO 2 emissions, 8,9 which in turn contributes to global warming and brings a grievous threat to the environment and health of living things on earth. [10][11][12] Worldwide, the development of degradable materials, [13][14][15] has become the "hot spot" to deal with the ecological and environmental problems caused by nondegradable plastics. 16,17 Poly (glycolic acid) (PGA), 18,19 a synthetic polymer material with high-level biodegradability, makes it an ideal and versatile material for developing biodegradable and bio-mass derived plastics to replace nondegradable plastics.…”