Abstract:In
this study, two trigonal prisms based on the 1,3,5-triazine
motif (SA and SB), distinguished by hydrophobic
groups, were prepared by the self-assembly of tritopic terpyridine
ligands and Zn(II) ions. SA and SB exhibited
high luminescence efficiencies in the solid state, overcoming the
fluorescence quenching of the 1,3,5-triazine group caused by π–π
interactions. Notably, SA and SB exhibited
different luminescence behaviors in the solution state and aggregation
state. SB with 12 alkyl chains exhibited extrem… Show more
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