Constructing zigzag-like hollow mesoporous nanospheres MoO₂/C with superior lithium storage performance

Abstract

Hollow mesoporous nanospheres MoO2/C are successfully constructed through metal chelating reaction between molybdenum acetylacetone and glycerol as well as the Kirkendall effect induced by diammonium hydrogen phosphate. MoO2 nanoparticles coupled by amorphous carbon are assembled to unique zigzag-like hollow mesoporous nanosphere with large specific surface area of 147.7 m2 g-1 and main pore size of 8.7 nm. The content of carbon is 9.1%. As anode material for lithium-ion batteries, the composite shows high specific capacity and excellent cycling performance. At 0.2 A g-1, average discharge capacity stabilizes at 1092 mAh g-1. At 1 A g-1 after 700 cycles, the discharge capacity still reaches 512 mAh g-1. Impressively, the composite preserves intact after 700 cycles. Even at 5 A g-1, the discharge capacity can reach 321 mAh g-1, exhibiting superior rate capability. Various kinetics analyses demonstrate that in electrochemical reaction, the proportion of the surface capacitive effect is higher, and the composite has relatively high diffusion coefficient of Li ions and fast faradic reaction kinetics. Excellent lithium storge performance is attributed to the synergistic effect of zigzag-like hollow mesoporous nanosphere and amorphous carbon, which improves reaction kinetics, structure stability and electronic conductivity of MoO2. The present work provides a new useful structure design strategy for advanced energy storage application of MoO2.

Amorphous MoO2/C Nanospheres–Porous Graphene Composites for Pseudocapacitive Li Storage

“…More importantly, our method does not involve multistep carbon coating and complex interface modification, potentially advancing to production scale. When compared with previously reported MoO 2 -C nanocomposites, − the well-designed MoO 2 /C-rGO exhibits several unique advantages, such as oxygen-deficient amorphous nanostructure, open diffusion channels, and continuous conductive networks. In virtue of the desirable structural engineering, the composite manifests extraordinary specific capacity, excellent cyclability, and fast pseudocapacitive Li storage capability.…”