Li–S
batteries with high energy density are considered to
be some of the most promising energy storage devices. However, the
shuttle effect, sluggish kinetics, and volume expansion problems of
lithium polysulfides (LiPSs) have severely limited their industrial
applications. In this work, porous hollow carbon nanospheres (HCNSs)
with tunable microstructures were designed by replacing resorcinol
with an ethanol-soluble portion (ESP) from lignites rich in heteroatoms
and alkyl side chains and employed as cathodes for Li–S batteries.
The results show that the specific surface area, defect, and heteroatoms
significantly increase after introducing ESP, thus promoting the adsorption
and conversion of LiPSs. S@HCNS-30 exhibits the best electrochemical
performance with a high initial discharge specific capacity of 1253.2
and 782.7 mAh·g–1 at 0.1C and 2C, respectively,
and a low decay rate of 0.075% per cycle after 500 cycles, which is
much superior to S@HCNS from pure resorcinol and many other coal-
or biomass-derived carbon materials. In addition, a high discharge
specific capacity of 659.9 mAh·g–1 was achieved
under challenging conditions of a depleted electrolyte (E/S = 10 μL·mg–1) and high areal density (5.3 mg·cm–2). This work not only contributes to the high-value utilization of
lignites but also provides a facile approach for high-performance
cathodes for Li–S batteries.