Constructing Fireproof MXene-Based Cotton Fabric/Thermoplastic Polyurethane Hierarchical Composites via Encapsulation Strategy

Abstract

Promising cotton fabric composites are designed to be protected by flame retardant thermoplastic polyurethane (TPU) composites for the next-generation fire-proof suit. Herein, we successfully constructed flexible cotton/TPU hierarchical composites, where a comfortable cotton internal layer was obtained by multiple dip coating of titanium carbide (MXene) and ammonium polyphosphate (APP)/TPU composites served as external layers. The flame retardant and mechanical properties of its cotton/TPU hierarchical composites were tuned by adjusting the dip coating circle. The obtained thermogravimetric analysis results of the TPU/APP/Cn system indicated that the char residue of MXenebased cotton/TPU hierarchical composites by third dip coating increased from 9.81 to 30.81 wt %. Notably, the hierarchical composites showed 87.2% and 65% reductions in the peak of heat release rate and total heat release, respectively, compared to pure TPU. Besides, their mechanical performance was improved significantly, e.g. the tensile strength, elongation at break, and toughness reaching 20 MPa, 400%, and 30.0 MJ/m 3 , respectively. These properties improvements are due to the synergistic effect between MXene-based cotton and TPU/APP composites. This work offers a promising attempt for the design of flexible and multifunctional cotton/polymer hierarchical composites with brilliant flame retardancy and mechanical properties.

Boron-Based Polyphosphazene-Functionalized Mxene Nanosheets for Polypropylene Composites with Improved Mechanical Properties and Flame Retardancy Applications

“…In terms of smoke release (Figure c,d), the TSP data indicate that the TSP values of PP8 and PP9 are 0.77 and 0.45 m 2 , significantly lower than the TSP of PP2 (2.73 m 2 ). This suggests that the Ti 3 C 2 T x structure possesses remarkable condensed-phase flame retardancy, wherein its layered barrier effect and catalytic charring ability promote the trapping and fixation of carbon particles into a char layer . However, the smoke release from Ti 3 C 2 T x @PPD is slightly enhanced, because DA was used as the graft monomer to keep phosphorus in a lower oxidation state in the polyphosphazene structure, resulting in increased release of phosphorus-containing volatiles. , This shows that the PPD structure has certain gas-phase flame-retardant properties.…”