Developing cost-efficient and noble
metal free electrocatalysts
is vastly anticipated for the oxygen evolution reaction (OER). Therefore,
in this study, to lift the thermodynamic and kinetic activity of the
OER, we attempted to synthesize a bimetallic nickel and manganese-based
zeolite imidazolate framework system in a fiber form. For this synthesis,
a bottom-up approach has been followed through wet chemical analysis,
and electrospinning was utilized for fiber formation. The resultant
fiber has shown a lesser overpotential of 256 mV at a benchmarking
current density of 10 mA cm–2 under 1 M KOH conditions.
As expected, the attained Tafel slope and charge transfer resistance
values are lesser. The observed results reveal that the synergism
between the Ni and Mn nodes on the imidazolate framework successfully
promotes the thermodynamic formation of *O and *OOH intermediates,
which significantly helps to improve the faster OER kinetics at the
electrode–electrolyte interface.