Construct electron transport path through NH2-MIL-125 modified Fe-doped W18O49 nanowires to enhance photocatalytic nitrogen fixation performance

Hou, Zhenhua; Wang, Libo; Liu, Gang; Wang, Ya; Wang, Yuhan; Zhang, Yangyang; Wu, Xiayu; Li, Nan

doi:10.1016/j.jallcom.2023.172940

Journal of Alloys and Compounds

2024

DOI: 10.1016/j.jallcom.2023.172940

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Construct electron transport path through NH2-MIL-125 modified Fe-doped W18O49 nanowires to enhance photocatalytic nitrogen fixation performance

Zhenhua Hou,

Libo Wang,

Gang Liu

et al.

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Cited by 3 publications

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Photo‐ and Photoelectrocatalysis in Nitrogen Reduction Reactions to Ammonia: Interfaces, Mechanisms, and Modeling Simulations

Ješić,

Pomeroy,

Kamal

et al. 2024

Adv Energy and Sustain Res

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The Haber–Bosch process is a cornerstone in the field of ammonia production and represents a decisive advance in industrial chemistry. This method, developed in the early 20th century, revolutionizes agriculture and enables the mass production of fertilizers. As the world strives for sustainable energy and environmental protection, alternative methods such as the photo/photoelectrocatalytic nitrogen reduction reaction (NRR) are gaining momentum. By using sunlight, electricity, or a combination of both, these approaches promise sustainable ammonia production with renewable energy sources and innovative materials. Researchers are trying to understand the underlying principles, mechanisms, and advances of these methods to overcome the challenges and optimize their effectiveness. This research is a step toward sustainable energy and agriculture, and offers a greener and more efficient way forward. This review looks at advances in sustainable ammonia production, particularly through photo‐ and photoelectrocatalytic NRRs. It examines the hurdles in implementing these methods and provides an overview of the fundamentals of nitrogen fixation and a comparison of current mechanisms. In addition, thermodynamic, theoretical, and computational studies of these processes are summarized. Various photocatalysts and photoelectrocatalysts used for ammonia production are also presented.

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Photo‐ and Photoelectrocatalysis in Nitrogen Reduction Reactions to Ammonia: Interfaces, Mechanisms, and Modeling Simulations

Ješić,

Pomeroy,

Kamal

et al. 2024

Adv Energy and Sustain Res

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Synergistic effect of bimetallic active sites on Ce doped NH2–MIL-125 for promoting photocatalytic conversion of nitrogen to NH3

Wang,

Hou

et al. 2024

Journal of Alloys and Compounds

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In situ construction of the W18O49/Mn0.45Cd0.55S S-scheme heterojunction for enhanced photocatalytic hydrogen generation

Niu,

Yang,

Kong

et al. 2024

Materials Science in Semiconductor Processing

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Construct electron transport path through NH2-MIL-125 modified Fe-doped W18O49 nanowires to enhance photocatalytic nitrogen fixation performance

Cited by 3 publications

References 34 publications

Photo‐ and Photoelectrocatalysis in Nitrogen Reduction Reactions to Ammonia: Interfaces, Mechanisms, and Modeling Simulations

Photo‐ and Photoelectrocatalysis in Nitrogen Reduction Reactions to Ammonia: Interfaces, Mechanisms, and Modeling Simulations

Synergistic effect of bimetallic active sites on Ce doped NH2–MIL-125 for promoting photocatalytic conversion of nitrogen to NH3

In situ construction of the W18O49/Mn0.45Cd0.55S S-scheme heterojunction for enhanced photocatalytic hydrogen generation

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