Connecting the unstable region of the entropy to the pattern of the Fisher zeros map

Abstract

Phase transitions are one of the most interesting natural phenomena. For finite systems, one of the concerns in the topic is how to classify a specific transition as a being of first, second, or even of a higher order according to the Ehrenfest classification. The partition function provides all the thermodynamic information about the physical systems, and a phase transition can be identified using the complex temperature where it is equal to zero. In addition, the pattern of zeros in the complex temperature plane can provide evidence of the transition order. This manuscript presents an analytical and simulational study connecting the microcanonical analysis of the unstable region of the entropy to the canonical partition function zeros. We show that, for the first-order transition, the zeros accumulate uniformly in a vertical line on the complex inverse temperature plane as discussed in previous works. We illustrate our calculations using a 147 particles Lennard-Jones cluster.