Abstract:The
shapeshifting behavior for synthetic matters was found at either
the molecular or supramolecular level, but the connection between
shapeshifting at the two hierarchical levels remains missing. In this
study, an 8-arm star giant molecule, NPOSS, was synthesized
to connect the molecular and supramolecular shapeshifting. Controlling
the conditions of bulk self-assembly allowed us to bring NPOSS into three different Ostwald’s stages of nucleation. The
high conformational flexibility of NPOSS facilitates
molecu… Show more
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