Connecting 16- with 4-Membered Rings: Ring-Opening Polymerization of Bio-Based ω-Pentadecalactone with Amino-Alkoxy-Bis(phenolate) Yttrium Initiators and Copolymerization with β-Butyrolactone

Hornberger, Lea-Sophie; Weingarten, Philipp; Lange, Pia L.; Schleid, Thomas; Adams, Friederike

doi:10.1016/j.eurpolymj.2023.112449

European Polymer Journal

2023

DOI: 10.1016/j.eurpolymj.2023.112449

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Connecting 16- with 4-Membered Rings: Ring-Opening Polymerization of Bio-Based ω-Pentadecalactone with Amino-Alkoxy-Bis(phenolate) Yttrium Initiators and Copolymerization with β-Butyrolactone

Lea-Sophie Hornberger,

Philipp Weingarten,

Pia L. Lange

et al.

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2024

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Merging σ‐Bond Metathesis with Polymerization Catalysis: Insights into Rare‐Earth Metal Complexes, End‐Group Functionalization, and Application Prospects

Adams

2024

Macromol. Rapid Commun.

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Polymers with well‐defined structures, synthesized through metal‐catalyzed processes, and having end groups exhibiting different polarity and reactivity than the backbone, are gaining considerable attention in both scientific and industrial communities. These polymers show potential applications as fundamental building blocks and additives in the creation of innovative functional materials. Investigations are directed toward identifying the most optimal and uncomplicated synthetic approach by employing a combination of living coordination polymerization mediated by rare‐earth metal complexes and C–H bond activation reaction by σ‐bond metathesis. This combination directly yields catalysts with diverse functional groups from a single precursor, enabling the production of terminal‐functionalized polymers without the need for sequential reactions, such as termination reactions. The utilization of this innovative methodology allows for precise control over end‐group functionalities, providing a versatile approach to tailor the properties and applications of the resulting polymers. This perspective discusses the principles, challenges, and potential advancements associated with this synthetic strategy, highlighting its significance in advancing the interface of metalorganic chemistry, polymer chemistry, and materials science.

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Merging σ‐Bond Metathesis with Polymerization Catalysis: Insights into Rare‐Earth Metal Complexes, End‐Group Functionalization, and Application Prospects

Adams

2024

Macromol. Rapid Commun.

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Connecting 16- with 4-Membered Rings: Ring-Opening Polymerization of Bio-Based ω-Pentadecalactone with Amino-Alkoxy-Bis(phenolate) Yttrium Initiators and Copolymerization with β-Butyrolactone

Cited by 1 publication

References 62 publications

Merging σ‐Bond Metathesis with Polymerization Catalysis: Insights into Rare‐Earth Metal Complexes, End‐Group Functionalization, and Application Prospects

Merging σ‐Bond Metathesis with Polymerization Catalysis: Insights into Rare‐Earth Metal Complexes, End‐Group Functionalization, and Application Prospects

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