Abstract:The chemistry of boron-containing molecules pervades the study of biomolecules, new materials, organic synthesis, and beyond. In addition, the stereochemistry and rehybridization capability of boron in molecules influence the reactivity and selectivity of reactions. Therefore, conformational analysis and the study of substituent effects on the modulation of the sp 2 -sp 3 character of boron in β-substituted ethylboranes may be valuable for the rational design of compounds in which the empty p B orbital plays a… Show more
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