Conformational analysis of 2-aminophenyl-, 2-aminobenzyl-, and 2-nitrobenzyl(diphenyl)phosphine oxides

Vereshchagina, Ya. A.; Alimova, A. Z.; Чачков, Д. В.; Ishmaeva, E. A.; Аrtyushin, О. I.; Шарова, Е. В.; Klimovitskii, Alexander E.; Khanafieva, R. R.

doi:10.1134/s1070428014060062

Russ J Org Chem

2014

DOI: 10.1134/s1070428014060062

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Conformational analysis of 2-aminophenyl-, 2-aminobenzyl-, and 2-nitrobenzyl(diphenyl)phosphine oxides

Ya. A. Vereshchagina

A. Z. Alimova

Д. В. Чачков

et al.

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“…Conformational analysis of 2-aminophenyl-, 2-aminobenzyl-, and 2-nitrobenzyl(diphenyl)phosphine oxides by the dipole moment, vibrational spectroscopy, and quantum chemical methods [4] has shown that phosphine oxide derivatives with a primary amino group exist as only one conformer with intramolecular hydrogen bond.…”

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Synthesis, polarity, and structure of 2-chloro-N-[2-(methylsulfanyl)phenyl]- and 2-(diphenylthiophosphoryl)-N-[2-(methylsulfanyl)phenyl]acetamides

et al. 2015

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Conformations of 2-chloro-N-[2-(methylsulfanyl)phenyl]-and 2-(diphenylthiophosphoryl)-N-[2-(methylsulfanyl)phenyl]acetamides have been studied by the dipole moment method and quantum chemical calculations. 2-(Diphenylthiophosphoryl)-N-[2-(methylsulfanyl)phenyl]acetamide has been found to exist as an equilibrium mixture of two conformers with synclinal and anticlinal orientations of the C sp 3-C sp 2 and P=S bonds. 2-Chloro-N-[2-(methylsulfanyl)phenyl]acetamide is represented by one preferred conformer.

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confidence: 99%

Synthesis, polarity, and structure of 2-chloro-N-[2-(methylsulfanyl)phenyl]- and 2-(diphenylthiophosphoryl)-N-[2-(methylsulfanyl)phenyl]acetamides

et al. 2015

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Conformational analysis of 2-aminophenyl-, 2-aminobenzyl-, and 2-nitrobenzyl(diphenyl)phosphine oxides

Cited by 1 publication

References 6 publications

Synthesis, polarity, and structure of 2-chloro-N-[2-(methylsulfanyl)phenyl]- and 2-(diphenylthiophosphoryl)-N-[2-(methylsulfanyl)phenyl]acetamides

Synthesis, polarity, and structure of 2-chloro-N-[2-(methylsulfanyl)phenyl]- and 2-(diphenylthiophosphoryl)-N-[2-(methylsulfanyl)phenyl]acetamides

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