In the last decade, imaging techniques capable of reconstructing three dimensional pore-scale model have played a pivotal role in the study of fluid flow through complex porous media. In this study, we present advances in the application of Confocal Laser Scanning Microscopy (CLSM) to image, reconstruct and characterize complex porous geological materials with hydrocarbon reservoir and CO 2 storage potential. CLSM has a unique capability of producing three dimensional (3-D) thin optical sections of a material, with a wide field of view and submicron resolution in the lateral and axial planes. However, CLSM is limited in the depth (zdimension) that can be imaged in porous materials. In this study, we introduce a 'grind and slice' technique to overcome this limitation. We discuss the practical and technical aspects of the confocal imaging technique with application to complex rock samples including Mt.Gambier and Ketton carbonates. We then describe the complete work-flow of image processing to filtering and segmenting the raw 3-D confocal volumetric data into pores and grains. Finally, we use the resulting 3-D pore-scale binarized confocal data obtained to quantitatively determine petrophysical pore-scale properties such as total porosity, macroand micro-porosity and single-phase permeability using lattice Boltzmann (LB) simulations, validated by experiments.1 saurabh.shah10@imperial.ac.uk